Novel metal complex and method for producing alpha-olefin polymer and method for producing alpha-olefin/(meth)acrylate copolymer using the same
AssigneesJapan Polypropylene Corporation, Japan Polyethylene Corporation
InventorsFumihiko Shimizu, Shixuan Xin, Akio Tanna, Shiho Goromaru, Koushi Matsubara
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Abstract
A novel catalyst component for producing a crystalline α-olefin polymer or α-olefin/(meth)acrylate copolymer having few branches, especially a polymer having a high molecular weight, and a method for producing an α-olefin polymer or an α-olefin/(meth)acrylate copolymer using the catalyst component. A metal complex represented by the following general formula (D), as well as a method for producing an α-olefin polymer and a method for producing an α-olefin/(meth)acrylate copolymer using the metal complex.
Claims10
A metal complex represented by the following general formula (D):
- [wherein M represents a transition metal belonging to 9th, 10th or 11th group in the periodic table. R3 represents hydrogen or hydrocarbon group having 1 to 20 carbon atoms and optionally containing a hetero atom. L1 represents a ligand coordinated to M. In addition, R3 and L1 may bind each other to form a ring. X1 represents oxygen or sulfur. E1 represents phosphorus, arsenic or antimony. R4 represents each independently hydrogen or hydrocarbon group having 1 to 20 carbon atoms and optionally containing a hetero atom, wherein at least one of R4 is hydrocarbon group having two or more hetero-atom-containing groups. R10, R11, R12 and R13 represent each independently hydrogen, halogen, hydrocarbon group having 1 to 30 carbon atoms and optionally containing a hetero atom, OR2, CO2R2, CO2M′, C(O)N(R1)2, C(O)R2, SR2, SO2R2, SOR2, OSO2R2, P(O)(OR2)2-y(R1)y, CN, NHR2, N(R2)2, Si(OR1)3-x(R1)x, OSi(OR1)3-x(R1)x, NO2, SO3M′, PO3M′2, P(O)(OR2)2M′ or epoxy containing group. Here, R1 represents hydrogen or hydrocarbon group having 1 to 20 carbon atoms. In addition, R2 represents hydrocarbon group having 1 to 20 carbon atoms. M′ represents alkali metal, alkaline earth metal, ammonium, quaternary ammonium or phosphonium, x represents an integer of 0 to 3, and y represents an integer of 0 to 2. It should be noted that, a plurality of groups properly selected from R4, R10, R11, R12 and R13 may bind each other to form aliphatic ring, aromatic ring, or hetero ring containing hetero atom selected from oxygen, nitrogen and sulfur. In this case, number of ring member is 5 to 8, and the ring optionally has substituent thereon.]
Dependencies are inferred from the claim text.