Heterocyclic Compounds as Pesticides
AssigneeBayer CropScience AG
InventorsThomas Bretschneider, Eva-Maria Franken, Ulrich Görgens, Martin Füßlein, Achim Hense, Joachim Kluth, Hans-Georg Schwarz, Adeline Köhler, Olga Malsam, Arnd Voerste, Angela Becker
Life of this patent
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Abstract
The present application relates to the use of heterocyclic compounds, some of which are known, for controlling animal pests, including arthropods and in particular insects, furthermore to novel heterocyclic compounds and to processes for their preparation.
Claims20
1-9. (canceled)
A method for controlling a pest comprising applying a compound of formula (I)
- in which
- (Ia)
- G1 represents N, CH or C-halogen,
- G2 represents
- in which
- R1 represents hydrogen or alkyl and
- G3 represents optionally substituted heterocyclyl, represents optionally substituted heteroaryl or represents optionally substituted aryl or
- (Ib)
- G1 represents N or C-halogen,
- G2 represents
- in which
- G3 represents optionally substituted heterocyclyl, represents optionally substituted heteroaryl or represents optionally substituted aryl or
- (Ic)
- G1 represents CH,
- G2 represents
- in which
- G3 represents optionally substituted heterocyclyl or represents substituted furanyl or represents thienyl which is substituted by halogen, nitro, amino, alkylamino, dialkylamino, haloalkyl, cycloalkylalkyl, alkoxy, haloalkoxy, alkylthio, alkoxyalkyl, bis(alkoxy)alkyl, alkoxycarbonyl, alpha-hydroxyimino-alkoxycarbonylmethyl, alpha-alkoxyiminoalkoxycarbonylmethyl, C(X) NR2R3, (in which X represents oxygen or sulphur, R2 represents hydrogen or alkyl and R3 represents alkyl, haloalkyl, alkoxy, cyanoalkyl, alkynyl, cycloalkyl, cycloalkylalkyl, alkoxyalkyl, alkylthioalkyl or arylalkyl or R2 and R3 together with the nitrogen atom to which they are attached form a ring), alkylsulphinyl, alkylsulphonyl, heterocyclyl, aryl (which for its part may be substituted by halogen, cyano, nitro, alkyl or haloalkyl), heteroaryl (which for its part may be substituted by halogen, nitro, alkyl, haloalkyl, alkoxy, haloalkoxy, alkoxyalkyl, alkylthio, alkylthioalkyl or cycloalkyl), heteroarylalkyl (which for its part may be substituted by halogen, nitro, alkyl, haloalkyl, alkoxy, haloalkoxy, alkoxyalkyl, alkylthio, alkylthioalkyl or cycloalkyl) or represents in each case optionally substituted hetaryl from the group consisting of pyrrolyl, pyrazolyl, imidazolyl, 1,2,3-triazolyl, 1,2,4-triazolyl, oxazolyl, isoxazolyl, thiazolyl, isothiazolyl, 1,2,3-oxadiazolyl, 1,2,4-oxadiazolyl, 1,3,4-oxadiazolyl, 1,2,5-oxadiazolyl, 1,2,3-thiadiazolyl, 1,2,4-thiadiazolyl, 1,3,4-thiadiazolyl, 1,2,5-thiadiazolyl, pyridyl, pyrimidinyl, pyridazinyl, pyrazinyl, 1,2,3-triazinyl, 1,2,4-triazinyl, 1,3,5-triazinyl, benzofuryl, benzisofuryl, benzothienyl, benzisothienyl, indolyl, isoindolyl, indazolyl, benzothiazolyl, benzisothiazolyl, benzoxazolyl, benzisoxazolyl, benzimidazolyl, 2,1,3-benzoxadiazole, quinolinyl, isoquinolinyl, cinnolinyl, phthalazinyl, quinazolinyl, quinoxalinyl, naphthyridinyl, benzotriazinyl, purinyl, pteridinyl and indolizinyl or represents cyano-, nitro-, haloalkoxy- or heterocyclyl-substituted aryl or
- (Id)
- G1 represents N, CH or C-halogen,
- G2 represents
- in which
- R1 represents hydrogen or alkyl and
- G3 represents optionally substituted heterocyclyl or represents optionally substituted heteroaryl or represents optionally substituted aryl,
- or a salts, metal oxides or N-oxides thereof to said pest and/or its habitat.
A compound of formula (IA)
- in which
- G1 represents N, CH or C-halogen,
- R1 represents hydrogen, and
- G3 represents optionally substituted heterocyclyl, represents optionally substituted heteroaryl or represents optionally substituted aryl.
A compound of formula (IB-I)
- in which
- G1 represents N or C-halogen and
- G3 represents optionally substituted heterocyclyl, represents optionally substituted heteroaryl or represents optionally substituted phenyl.
A compound of formula (IB-2)
- in which
- G1 represents C—H and
- G3 represents in each case optionally halogen-, cyano-, nitro-, alkyl-, haloalkyl-, cycloalkyl-, alkoxy-, haloalkoxy-, alkylthio-, haloalkylthio-, alkylsulphinyl-, alkylsulphonyl-, haloalkylsulphinyl-, haloalkylsulphonyl-, amino-, alkylamino-, dialkylamino-, alkylcarbonylamino-, alkoxycarbonylamino-, alkoxyalkyl-, haloalkoxyalkyl-, alkenyl-, alkynyl-, alkylcycloalkyl-, alkylcarbonyl-, alkoxycarbonyl-, aminocarbonyl-, pyridyl- or pyrimidyl-substituted oxazolinyl, dihydrooxadiazinyl, dihydrodioxazinyl or hydroxypyridyl or
- represents furanyl, thienyl or pyridyl, each of which is substituted by fluorine, nitro, amino, alkylamino, dialkylamino, haloalkyl, cycloalkylalkyl, haloalkoxy, alkylthio, alkoxyalkyl, bis(alkoxy)alkyl, alkoxycarbonyl, alpha-hydroxyiminoalkoxycarbonylmethyl, alpha-alkoxyiminoalkoxycarbonylmethyl, C(X)NR2R3, (in which X represents oxygen or sulphur, R2 represents hydrogen or alkyl and R3 represents alkyl, haloalkyl, alkoxy, cyanoalkyl, alkynyl, cycloalkyl, cycloalkylalkyl, alkoxyalkyl, alkylthioalkyl or arylalkyl), alkylsulphinyl, alkylsulphonyl, the heterocyclyl radicals morpholinyl, triazolinonyl, dihydrodioxazinyl, dihydrooxadiazinyl, dioxolanyl, dioxanyl, piperidinonyl, pyrrolidinonyl and pyrazolinonyl (which for their part may be substituted by alkyl or haloalkyl), phenyl (which for its part may be substituted by halogen, cyano, nitro, alkyl or haloalkyl), the heteroaryl radicals pyrrolyl, pyridyl, pyridyl N-oxide, pyrimidyl, imidazolyl, pyrazolyl, oxazolyl, thiazolyl, furanyl, thienyl, triazolyl, oxadiazolyl, thiadiazolyl, pyrazinyl, triazinyl, tetrazinyl and isoquinolinyl (which for their part may be substituted by halogen, nitro, alkyl, haloalkyl, alkoxy, haloalkoxy, alkoxyalkyl, alkylthio, alkylthioalkyl and cycloalkyl), the heteroarylalkyl radicals triazolylalkyl, pyridylalkyl, pyrimidylalkyl or oxadiazolylalkyl (which for their part may be substituted by alkyl) or
- represents pyrrolyl, pyrazolyl, imidazolyl, 1,2,3-triazolyl, 1,2,4-triazolyl, oxazolyl, isoxazolyl, thiazolyl, isothiazolyl, 1,2,3-oxadiazolyl, 1,2,4-oxadiazolyl, 1,3,4-oxadiazolyl, 1,2,3-thiadiazolyl, 1,2,4-thiadiazolyl, 1,3,4-thiadiazolyl, 1,2,5-thiadiazolyl, pyrimidinyl, pyridazinyl, pyrazinyl, 1,2,3-triazinyl, 1,2,4-triazinyl, 1,3,5-triazinyl, benzofuryl, benzisofuryl, benzothienyl, benzisothienyl, indolyl, isoindolyl, indazolyl, benzothiazolyl, benzisothiazolyl, benzoxazolyl, benzisoxazolyl, benzimidazolyl, 2,1,3-benzoxadiazole, quinolinyl, isoquinolinyl, cinnolinyl, phthalazinyl, quinazolinyl, quinoxalinyl, naphthyridinyl, benzotriazinyl, purinyl, pteridinyl or indolizinyl, each of which is optionally substituted by halogen, nitro, amino, alkylamino, dialkylamino, alkyl, haloalkyl, cycloalkylalkyl, alkoxy, haloalkoxy, alkylthio, alkoxyalkyl, bis(alkoxy)alkyl, alkoxycarbonyl, alpha-hydroxyiminoalkoxycarbonylmethyl, alpha-alkoxyiminoalkoxycarbonylmethyl, C(X)NR2R3, (in which X represents oxygen or sulphur, R2 represents hydrogen or alkyl and R3 represents alkyl, haloalkyl, alkoxy, cyanoalkyl, alkynyl, cycloalkyl, cycloalkylalkyl, alkoxyalkyl, alkylthioalkyl or arylalkyl), alkylsulphinyl, alkylsulphonyl, the heterocyclyl radicals morpholinyl, triazolinonyl, dihydrodioxazinyl, dihydrooxadiazinyl, dioxolanyl, dioxanyl, piperidinonyl, pyrrolidinonyl and pyrazolinonyl (which for their part may be substituted by alkyl or haloalkyl), phenyl (which for its part may be substituted by halogen, cyano, nitro, alkyl or haloalkyl), the heteroaryl radicals pyrrolyl, pyridyl, pyridyl N-oxide, pyrimidyl, imidazolyl, pyrazolyl, oxazolyl, thiazolyl, furanyl, thienyl, triazolyl, oxadiazolyl, thiadiazolyl, pyrazinyl, triazinyl, tetrazinyl and isoquinolinyl (which for their part may be substituted by halogen, nitro, alkyl, haloalkyl, alkoxy, haloalkoxy, alkoxyalkyl, alkylthio, alkylthioalkyl or cycloalkyl), the heteroarylalkyl radicals triazolylalkyl, pyridylalkyl, pyrimidylalkyl or oxadiazolylalkyl (which for their part may be substituted by alkyl) or
- represents cyano-, nitro-, haloalkoxy-, dioxolanyl-, piperidinonyl-, pyrrolidinonyl- or dihydrodioxazinyl-substituted phenyl.
A compound of formula (IC-1)
- in which
- G1 represents C—H,
- R1 represents alkyl, and
- G3 represents optionally substituted heterocyclyl, represents optionally substituted heteroaryl or represents optionally substituted phenyl.
A compound of formula (IC-2)
- in which
- G1 represents C—H,
- R1 represents hydrogen, and
- G3 represents optionally substituted heterocyclyl, represents optionally substituted heteroaryl or represents optionally alkyl-, haloalkyl-, haloalkoxy-, dioxolanyl- or dihydrodioxazinyl-substituted phenyl.
A compound of formula (IC-3)
- in which
- G1 represents N or C-halogen,
- R1 represents hydrogen or alkyl, and
- G3 represents optionally substituted heterocyclyl, represents optionally substituted heteroaryl or represents optionally substituted phenyl.
Dependencies are inferred from the claim text.