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US 2011/0212391 A1Published application
Polymer, chemically amplified positive resist composition and pattern forming process
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsKeiichi Masunaga, Satoshi Watanabe, Jun Hatakeyama, Youichi Ohsawa, Daisuke Domon
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Abstract
A polymer comprising recurring units having a fluorinated carboxylic acid onium salt structure on a side chain is used to formulate a chemically amplified positive resist composition. When the composition is processed by lithography to form a positive pattern, the diffusion of acid in the resist film is uniform and slow, and the pattern is improved in LER.
Claims12
A polymer comprising recurring units of a fluorinated carboxylic acid onium salt having the general formula (1):
- wherein R1 is a structure derived from a basis skeleton capable of providing the polymerization activity of a polymerizable monomer, represented by any one of the formulae:
- wherein the valence bond extending from the oxygen atom in the structure designates a bond to W1,
- R2 is fluorine or a fluoroalkyl group,
- W1 is a divalent organic group, and
- Q+ is a sulfonium cation of the general formula (a) or (b) or a iodonium cation of the general formula (c):
- wherein R3, R4 and R5 are each independently a substituted or unsubstituted, straight or branched C1-C10 alkyl, alkenyl or oxoalkyl group or a substituted or unsubstituted C6-C18 aryl, aralkyl or aryloxoalkyl group, or at least two of R3, R4 and R5 may bond together to form a ring with the sulfur atom,
- wherein R6 is a substituted or unsubstituted, straight, branched or cyclic C1-C20 alkyl or alkenyl group or a substituted or unsubstituted C6-C14 aryl group, m is an integer of 1 to 5, n is 0 or 1, R6 may have a carbonyl group, hydroxyl group, ester structure, lactone structure, amino group, amide group or ether-bonding oxygen atom substituted thereon,
- wherein R6 is a substituted or unsubstituted, straight, branched or cyclic C1-C20 alkyl or alkenyl group or a substituted or unsubstituted C6-C14 aryl group, m is an integer of 1 to 5, n is 0 or 1, R6 may have a carbonyl group, hydroxyl group, ester structure, lactone structure, amino group, amide group or ether-bonding oxygen atom substituted thereon.
5 more elements
Dependencies are inferred from the claim text.