A refrigeration cycle apparatus in which a non-azeotropic refrigerant mixture circulates through a refrigeration cycle configured by a compressor, a condenser, a first decompressor, a vapor/liquid separator, a second decompressor and an evaporator which are connected sequentially, the non-azeotropic refrigerant mixture consisting of a high-boiling refrigerant and a or some low-boiling refrigerant(s) mixed at a predetermined mixing ratio, the apparatus comprising a controller for variably adjusting a pressure in said vapor/liquid separator by controlling opening of said first decompressor and said second decompressor, and determining the mixing ratio of said high-boiling refrigerant and said low-boiling refrigerant of said non-azeotropic refrigerant mixture so that a saturated vapor line where a gauge pressure that suppresses refrigerant decomposition due to incorporation of the fluid is 0.00 MPa is not to be higher than −45° C. in a low-pressure circuit formed between said second decompressor and said compressor.