Copolymers with amorphous polyamide segments
AssigneeDow Global Technologies LLC
InventorsWilliam J. Harris, Jerry E. White
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Abstract
The invention, in one aspect, is a copolymer comprising amorphous polyamide hard segments, which contain 1-methyl-2,4-phenylene, 1-methyl-2,6-phenylene, or mixtures thereof structure units. The structure characteristics of 1-methyl-2,4-phenylene, 1-methyl-2,6-phenylene, or mixtures thereof render the hard segments having glass transition temperatures below 200° C. while maintaining physical properties required for making molded articles.
Claims18
A copolymer comprising a repeat unit of formula (I) and at least one of the following additional repeat units of formulae (II and III):
- wherein:
- at least from about 20% to about 90% of the copolymer is the repeat unit of formula (I),
- by weight based on the total weight of the copolymer;
- y independently is an integer from 1 to about 200;
- Z is oxygen;
- R1 is independently at each occurrence a C6-C24 divalent organic moiety, provided that in at least 55% of the occurrences of R1, R1 is independently at each occurrence a 1-methyl-2,4-phenylene or 1-methyl-2,6-phenylene;
- R2 is independently at each occurrence a bond or C1-C14 alkylene;
- R3 is independently at each occurrence a polyoxyalkylene having a number average molecular weight (Mn) from about 400 to about 10,000;
- and
- wherein the copolymer comprises at least one amorphous polyamide segment having from 2 to about 200 repeat units of formula (I).
17-22. (canceled)
Dependencies are inferred from the claim text.