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US 2011/0034652 A1Published application
Catalyst components based on ferrocenyl complexes used for olefin polymerisation
AssigneesTotal Petrochemicals Research Feluy, Centre National de la Recherche Scientifique (CNRS)
InventorsCyril Revault, Olivier Lavastre, Sabine Sirol
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Abstract
The present invention discloses catalyst components based on ferrocenyl ligands, their method of preparation and their use in the polymerization of olefins.
Claims13
An ferrocinium ligand of formula
- wherein Cp is a cyclopentadienyl group, unsubstituted or substituted, with chelating arms,
- wherein X and Y are the same or different with the restriction that at least one Y or X contains at least one chelating group in direct connection with the ferrocinium, the other of Y or X being optionally present and wherein X and/or Y are each independently selected to include atoms O, N, P, S or groups —CR═CR—, —CR═N—, —N═CR— or —C≡C— wherein R is H, alkyl or aryl groups having at most 20 carbon atoms,
- wherein Z and W are each independently selected from alkyl, aryl, heterocycle group or non-heterocycle group containing ether, thioether, phosphine, imine, amine or amide,
- wherein iron has been oxidated with an oxidant capable to oxidate FeII into FeIII but mild enough to preserve the ligand, and
- wherein A− is an anion associated to FeIII.
2 more elements
The oxidised ligand of any one of claims 1 to 3 wherein there is only one substituent group Y—Z or X—W, the other being hydrogen.
The oxidised ligand of any one of the preceding claims wherein oxidation is carried chemically.
Dependencies are inferred from the claim text.