Uzm-29 family of crystalline zeolitic compositions and a method of preparing the compositions

A process for preparing a microporous crystalline zeolite having a three dimensional structure of at least SiO2 tetrahedral units and having an empirical composition in the as-synthesized form and on an anhydrous basis expressed by an empirical formula of:

• Mmn+Rrp+Al1-xExSixOz
• where M is at least one exchangeable cation selected from the group consisting of alkali metal ions, alkaline earth metal ions, and rare earth metal ions, “m” is the mole ratio of M to (Al+E) and varies from greater than zero to about 2.0, R is an organoammonium cation or an amine selected from the group of pentaethonium ammonium, ethyltrimethylammonium (ETMA+), hexamethonium ammonium, diquat-4, pentyltrimethylammonium, choline, diethyldimethyl ammonium (DEDMA+), trimethylpropylammonium, dimethyldiethanolammonium, tetraethyl ammonium (TEA+), tetrapropylammonium (TPA+), dimethylhexylamine, diethanolamine, and mixtures thereof, “r” is the mole ratio of R to (Al+E) and has a value of about 0.25 to about 2.0, “n” is the weighted average valence of M and has a value of about 1 to about 3, “p” is the weighted average valence of R and has a value of about 1 to about 2, E is an element selected from the group consisting of gallium, iron, boron and mixtures thereof, “x” is the mole fraction of E and has a value from 0 to about 1.0, “y” is the mole ratio of Si to (Al+E) and varies from greater than 2 to about 10 and “z” is the mole ratio of O to (Al+E) and has a value determined by the equation:
• z=(m·n+p·r+3+4·y)/2
• and is characterized in that it has the x-ray diffraction pattern having at least the d-spacings and intensities set forth in Table A:
• TABLE A
• 2Θ
• d (Å)
• I/Io %
• 10.74-10.86
• 8.14-8.23
• w-m
• 12.50-12.6
• 6.99-7.07
• vs
• 16.60-16.72
• 5.30-5.33
• s-vs
• 17.48-17.7
• 5.01-5.07
• m
• 17.80-17.88
• 4.96-4.98
• w
• 20.74-20.81
• 4.26-4.28
• w
• 21.74-21.94
• 4.05-4.08
• m-s
• 22.82-22.88
• 3.88-3.89
• w-m
• 24.40-24.52
• 3.62-3.64
• w
• 25.08-25.10
• 3.54-3.55
• w
• 26.06-26.1
• 3.41-3.42
• w-m
• 27.10-27.12
• 3.28-3.29
• m
• 27.70-27.90
• 3.20-3.22
• m
• 28.26-28.44
• 3.14-3.15
• s-vs
• 30.00-30.30
• 2.94-2.97
• m
• 32.58-32.64
• 2.74-2.75
• w
• 33.02-33.03
• 2.71-2.71
• w
• 33.28-33.29
• 2.69-2.70
• m
• 33.76-33.82
• 2.65-2.65
• w
• 37.48-37.56
• 2.39-2.40
• w
• 41.20-42.41
• 2.13-2.19
• w
• 45.96-46.01
• 1.97-1.98
• w
• 51.4-52.00
• 1.70-1.77
• w
• 54.05-54.26
• 1.69-1.70
• w
• and is thermally stable up to a temperature of at least 400° C. the process comprising forming a reaction mixture containing reactive sources of M, R, Si and at least one of Al and E and heating the reaction mixture at a temperature of about 100° C. to about 200° C., for a time sufficient to form the composition, the reaction mixture having a composition expressed in terms of mole ratios of the oxides of:
• aM2/nO:bR2/pO:1-cAl2O3:cE2O3:dSiO2:eH2O
• where “a” has a value of greater than zero to about 2.0, “b” has a value of about 1.5 to about 120, “c” has a value of 0 to about 1.0, “d” has a value of about 2 to about 10, “e” has a value of about 25 to about 4000.

A microporous crystalline zeolite having a three-dimensional framework of at least AlO2 and SiO2 tetrahedral units and an empirical composition in an anhydrous basis of:

• M1′n+aAl(1-x)ExSiy′Oz″
• where M1 is at least one exchangeable cation selected from the group consisting of alkali, alkaline earth metals, rare earth metals, ammonium ion, hydrogen ion and mixtures thereof, “a” is the mole ratio of M1 to (Al+E) and varies from about 0.05 to about 50, “n” is the weighted average valence of M1 and has a value of about +1 to about +3, E is an element selected from the group consisting of gallium, iron, boron, and mixture thereof, “x” is the mole fraction of E and varies from 0 to 1.0, y′ is the mole ratio of Si to (Al+E) and varies from greater than about 3 to virtually pure silica and z′ is the mole ratio if O to (Al+E) and has a value determined by the equation:
• z′=(a·n+3+4·y′)/2
• the zeolite characterized in that it has an x-ray diffraction pattern having at least the d-spacings and relative intensities set forth in Table C.
• TABLE C
• 2Θ
• d (Å)
• I/Io %
• 10.86
• 8.14
• m
• 12.66
• 6.99
• vs
• 16.72
• 5.30
• m
• 17.70
• 5.01
• m
• 20.74
• 4.28
• w
• 21.94
• 4.05
• m
• 22.82
• 3.89
• w
• 24.52
• 3.63
• w
• 25.04
• 3.55
• w
• 26.06
• 3.416
• w
• 27.62
• 3.23
• w
• 27.70
• 3.22
• m
• 28.44
• 3.14
• m
• 30.30
• 2.95
• m
• 33.03
• 2.71
• w
• 33.76
• 2.65
• w
• 36.31
• 2.47
• w
• 37.48
• 2.40
• w
• 37.86
• 2.37
• w
• 40.96
• 2.20
• w
• 41.33
• 2.18
• w
• 42.41
• 2.13
• w
• 52.00
• 1.76
• w
• 53.86
• 1.70
• w
• 54.06
• 1.69
• w
• And is thermally stable up to a temperature of at least 400° C.