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US 2010/0305238 A1Published application
Dispersants for hydraulically setting systems
AssigneeSika Technology AG
InventorsChristina Hampel, Jabbar Al Shemari, Ulf Velten, Ueli Sulser
Life of this patent
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Abstract
The present invention relates to polymers P as dispersants, in particular as liquefiers, for hydraulically setting systems, and hydraulically setting systems comprising the polymer P. The polymer P comprises at least one acid unit, at least one ester unit, at least one unit containing a tetrahydrofurfuryl group, and optionally at least one amide unit.
Claims22
A polymer P having ester groups and comprising
- a) at least one structural unit A of the formula (I);
- b) at least one structural unit B of the formula (II);
- c) at least one structural unit C of the formula (III);
- optionally
- d) at least one structural unit D of the formula (IV);
- and optionally
- e) at least one further structural unit E;
- R1, independently of one another, being H, CH2COOM or an alkyl group having 1 to 5 carbon atoms,
- R2, independently of one another, being H, an alkyl group having 1 to 5 carbon atoms, COOM or CH2COOM;
- R3, independently of one another, being H, CH3, COOM or CH2COOM;
- and
- R4, independently of one another, being COOM;
- or R3 together with R4 forming a ring as —CO—O—CO—;
- M being H, a C1-C5 alkyl radical, alkali metal, alkaline earth metal or other di- or trivalent metal atoms, ammonium, an organic ammonium group or a mixture thereof;
- and R5, independently of one another, being
- R15 being —[(R11O)x—(R12O)y—(R13O)z]—R14;
- R11, R12 and R13, in each case independently of one another, being a C2-C4 alkylene group with an order of the (R11O), (R12O) and (R13O) units in any possible sequence;
- R14 being H, a C1-C12 alkyl or cycloalkyl radical, a C7-C20 alkylaryl or aralkyl radical, or a substituted or unsubstituted aryl radical;
- x, y, z, independently of one another, each having the values 0-250 and x+y+z being 3-250;
- R6, independently of one another, being H, CH3, COOM, CH2COOM or a substituent as defined for R5 or R7;
- in which R7, independently of one another, is a radical of the formula (V);
- in which R16, independently of one another, is NH, —NH—(R17)q—, O, or —O—(R18)s—,
- In which R17 and R18, in each case independently of one another, are a C1-C12 alkylene group or one or more C2-C4 oxyalkylene groups with an order in any possible sequence;
- in which q, independently of one another, is an integer and has the value 1 if R17 is a C1-C12 alkylene group and in each case has the value 1-150 if R17 is one or more C2-C4 oxyalkylene groups;
- in which s, independently of one another, is an integer and has the value 1 if R18 is a C1-C12 alkylene group and in each case has the value 1-150 if R18 is one or more C2-C4 oxyalkylene groups;
- R8, independently of one another, being H, CH3, COOM, CH2COOM or a substituent as defined for R5 or R7;
- R9 and R10 together forming a ring which optionally contains oxygen, sulfur or further nitrogen atoms;
- or R9 and R10, independently of one another, being H, a C1-C20 alkyl group, a C5-C9 cycloalkyl group, a C7-C12 aralkyl group, a hydroxyalkyl group or a compound of the formula (VI), (VII) or (VIII),
- R19, independently of one another, being an alkylene group and R20, independently of one another, being a C1- to C4-alkyl group, and
- X, independently of one another, being an S, O or N, where r=1 if X═S or O, or r=2 if X═N;
- R21 being an alkylene group optionally having heteroatoms;
- R11′, R12′ and R13′, in each case independently of one another, being a C2-C4 alkylene group with an order of the (R11′O), (R12′O) and (R13′O) units in any possible sequence;
- R14′ being a C1-C12 alkyl or cycloalkyl radical, a C7-C20 alkylaryl or aralkyl radical, or a substituted or unsubstituted aryl radical;
- and
- x′, y′, z′, independently of one another, having the values 0-100 and x′+y′+z′=1-100.
32 more elements
Dependencies are inferred from the claim text.