Stabilized etching solutions for cu and cu/ni layers
AssigneeBASF SE
InventorsMartin Fluegge, Raimund Mellies, Thomas Goelzenleuchter, Marianne Schwager, Ruediger Oesten
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Abstract
The present invention relates to new storage-stable solutions which can be used in semiconductor technology to effect specific etching of copper metallization layers and also Cu/Ni layers. With the new etch solutions it is possible to carry out etching and patterning of all-copper metallizations, layers of copper/nickel alloys, and also successive copper and nickel layers.
Claims7
1-7. (canceled)
A stabilized etch solution for etching copper layers and nickel layers, or layers of corresponding alloys, comprising nitric acid (HNO3), in an amount of 5% to 50% by weight, based on the overall composition, and hydrogen peroxide in an amount of 1% to 10% by weight, based on the overall composition, citric acid, and water.
The etch solution according to claim 1, comprising citric acid in an amount of 0.5% to 10% by weight, based on the overall composition.
The etch solution according to claim 1, comprising nitric acid (HNO3) in an amount of 15% to 35% by weight, based on the overall composition, hydrogen peroxide (H2O2) in an amount of 2% to 6% by weight, based on the overall composition, and citric acid in an amount of 2.5% to 6.5% by weight, based on the overall composition.
The etch solution according to, claim 1, comprising additives selected from the group consisting of wetting agents and/or surfactants.
An etch solution in semiconductor technology comprising the etch solution according to claim 1.
A process for etching successive copper layers and nickel layers in semiconductor technology, which comprises immersing semiconductor elements having corresponding layers in an etch solution according to claim 1 for a sufficiently long time and, after the metal layers have been etched away in a single step, removing the semiconductor elements from the etch solution, washing them with water, and drying them.
Dependencies are inferred from the claim text.