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US 2010/0304222 A1Published application
Electrolyte having eutectic mixture and nitrile compound, and electrochemical device containing the same
AssigneeLG Chem, Ltd.
InventorsJi-Won PARK, Byoung-Bae Lee, Jae-Seung Oh, Dong-Su Kim, Hyo-Jin Lee, Yeon-Suk Hong
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Abstract
Disclosed is an electrolyte comprising (a) a eutectic mixture of an amide compound represented by the following chemical formula 1 or 2 and an ionizable lithium salt; and (b) a nitrile compound. The eutectic mixture and the nitrile compound in the electrolyte contribute to excellent thermal and chemical stability and sufficiently low viscosity and high ion conductivity. The electrolyte can be usefully applied as an electrolyte of electrochemical devices.
Claims25
An electrolyte, comprising:
- (a) a eutectic mixture of an amide compound represented by the following chemical formula 1 or 2 and an ionizable lithium salt;
- and
- (b) a nitrile compound:
- where R, R1 and R2 are hydrogen, halogen or any one selected from the group consisting of alkyl group, alkylamine group, alkenyl group, alkoxy group, alkoxyalkyl group and aryl group, which is unsubstituted or substituted with halogen and has 1 to 20 carbons, independently, and
- X is any one selected from the group consisting of silicon, oxygen, nitrogen, phosphorus and sulfur, wherein i) m is 1 when X is oxygen or sulfur, ii) m is 2 when X is nitrogen or phosphorus, and iii) m is 3 when X is silicon,
- where R and R1 is hydrogen, or any one selected from the group consisting of alkyl group, alkylamine group, alkenyl group, aryl group, alkoxy group, alkoxyalkyl group and allyl group, which is unsubstituted or substituted with halogen and has 1 to 20 carbons, independently,
- X is any one selected from the group consisting of silicon, oxygen, nitrogen, phosphorus and sulfur, wherein i) m is 0 (zero) when X is oxygen or sulfur, ii) m is 1 when X is nitrogen or phosphorus, and iii) m is 2 when X is silicon, and
- n is an integer of 1 to 10.
5 more elements
Dependencies are inferred from the claim text.