High-temperature dual-source organic Rankine cycle with gas separations
AssigneeDoty Scientific, Inc.
InventorF. David Doty
Life of this patent
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AssigneeDoty Scientific, Inc.
InventorF. David Doty
Estimating the term…
In a dual-source organic Rankine cycle (DORC), the condensed and slightly sub-cooled working fluid at near ambient temperature (˜300 K) and at low-side pressure (0.1 to 0.7 MPa) is (1) pumped to high-side pressure (0.5-5 MPa), (2) pre-heated in a low-temperature (LT) recuperator, (3) boiled using a low-grade heat source, (4) super-heated in a high-temperature (HT) recuperator to a temperature close to the expander turbine exhaust temperature using this exhaust vapor enthalpy, (5) further super-heated to the turbine inlet temperature (TIT) using a mid-grade heat source, (6) expanded through a turbine expander to the low-side pressure, (7) cooled through the HT recuperator, (8) cooled through the LT recuperator, (9) mostly liquefied and slightly subcooled in a condenser, and (10) the condensed portion is returned to the pump to repeat this cycle.
A Dual-source Organic Rankine Cycle (DORC) for converting thermal power from the combination of a low-grade thermal source and a mid-grade thermal source to electrical power, said method characterized by:
The DORC of 1 further characterized in that the condensed working fluid in said condenser has mean molecular mass between 45 and 90.
The DORC of 1 further characterized as utilizing selective membranes and a vacuum pump for separation of non-condensable light gases from a vapor mixture in said condenser.
The DORC of 1 further characterized as including means for separating a portion of the heavy hydrocarbons (HHCs) from said working fluid, where HHCs arc defined as having molecular mass greater than 79 and normal boiling point greater than 354 K.
The DORC of 1 further characterized in that the condensed working fluid in said condenser has isobutane molar fraction greater than 0.2, benzene molar fraction greater than 0.01, and molar fraction less than 0.05 of other hydrocarbons having more than 5 carbon atoms.
The DORC of 1 further characterized as including a low-temperature (LT) recuperator for preheating said pressurized condensed working fluid using heat from the partially pre-cooled low-pressure vapor flow.
The DORC of 1 further characterized in that the ratio of the mass of its working fluid at temperature above (T6+T7)/2 to its total working fluid mass is less than 0.03.
The DORC of 1 further characterized as utilizing a first tank containing gravel and oil for low-grade sensible thermal storage and a second tank containing gravel and a high-boiling liquid for mid-grade sensible thermal storage.
The DORC of 1 further characterized in that the low-grade thermal source is selected from the set comprised of solar, geothermal, oceanic, and industrial waste.
The DORC of 1 further characterized in that surfaces of said final superheater and turbine which contact said working fluid are coated with a thin layer of material of low catalytic activity.
The DORC of 1 further characterized in that the mass fraction of lubricants in the condensed fluid in said boiler is greater than 0.003 but less than 0.03.
The DORC of 1 further characterized as utilizing a molten alloy comprised of at least 40% lead (Pb) for transferring heat into said final superheater.
The DORC of 1 in which said condenser is further characterized as comprising a plurality of cross-flow finned-tube heat exchangers in parallel.
The DORC of 4 in which the HHC separation process is further characterized as including:
The DORC of 6 in which said LT recuperator is further characterized as comprising a series of cross-flow finned-tube heat exchangers in a counter-flow arrangement.
The DORC of 7 further characterized in that:
The DORC of 8 in which said high-boiling liquid is further characterized as having normal boiling point greater than 660 K, autoignition temperature greater than 660 K, pour point below 320 K, and including a substantial component selected from the set comprised of polyphenyl ethers, polyalphaolefins, polyol esters, silicones, fluorocarbons, polymer esters, and alkylated polynuclear aromatics of normal boiling point greater than 660 K.
The DORC of 11 further characterized in that said lubricants are selected from the set comprised of alkylated benzenes and polyalphaolefins.
An Organic Rankine Cycle (ORC) for converting thermal power from a mid-grade thermal source to electrical power, said method characterized by:
Dependencies are inferred from the claim text.