Use of oxazine compounds for making chromogenic materials
AssigneeUniversity of Miami
InventorsMassimiliano Tomasulo, Francisco M. Raymo
Life of this patent
Estimating the term…
Loading patent…
AssigneeUniversity of Miami
InventorsMassimiliano Tomasulo, Francisco M. Raymo
Estimating the term…
Heterocyclic compounds incorporating a [1,3]oxazine ring may be used to make chromogenic materials. These molecules switch from a colorless state to a colored form upon addition of either acid or base. In both instances, the [1,3]oxazine ring opens in response to the pH change forming an indolium cation, after the addition of acid, or a phenolate anion, after the addition of base. Alternatively, the switch may occur in response to a change in electrical current or potential or a change in temperature. Chromophores absorb in the visible region of the electromagnetic spectrum. Hence, their formation translates into the appearance of color. These processes are fully reversible and the original colorless state can be regenerated by switching the pH back to neutral. Thus, these halochromic compounds can be used to develop displays, filters, indicators, lenses, sensors, switches, or windows able to switch their color in response to pH changes.
Use of a compound comprising indoline and benzooxazine fragments fused at the bond joining positions 1 and 2 of the indoline fragment to the bond joining positions 2 and 3 of the benzooxazine fragment to make a chromgenic material, wherein one or more of its optical properties change in response to at least pH, electrical, or thermal stimulus.
A method of switching reversibly optical properties of a compound or a material containing the compound by a change in electric current or potential, temperature, or pH;
An electrochromic, halochromic, or thermochromic compound of Formula I:
Dependencies are inferred from the claim text.