Process for the Production of Diols
AssigneeCognis IP Management GmbH
InventorsPeter McKenna, Mark Smallridge, Melissa Matthews, Simon Roberts
Life of this patent
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Abstract
The invention relates to a process for the production of diols with a special structure which are characterized by formula (I). These diols are substances which, besides two OH groups, contain a C═C double bond so that they are suitable as monomers for the production of polymers. The process comprises hydrolyzing a corresponding cyclic precursor in aqueous medium in the presence of an acid dissolved in that medium, the hydrolysis being accompanied by the elimination of a carbonyl compound, and subsequently neutralizing the acid present in the reaction mixture with a base, the base having a pKb value above 0.18 and preferably above 3.0 and being present in heterogeneous form.
Claims25
A process for the production of polymerizable monomers corresponding to formula (I):
- in which R1 is hydrogen or a C1-4 alkyl group,
- R2 to R4 independently represent hydrogen or an aliphatic, cycloaliphatic or aromatic moiety,
- X is a group —(CH2)n and n is the number 0 or 1,
- Y is a group —(CHR5)m and m is the number 0, 1 or 2, and R5 is hydrogen or an OH group,
- comprising the steps of:
- (a) hydrolyzing a compound corresponding to formula (II):
- in which the substituents R1, R2 to R4, X and Y are as defined above and the substituents R6 and R7 independently represent hydrogen or an aliphatic group,
- in aqueous medium and in the presence of an acid dissolved in the aqueous medium, the hydrolysis being accompanied by elimination of a compound (III):
- in which R6 and R7 are as defined above, to form a hydrolysis mixture, and
- (b) contacting said mixture with a weak base to neutralize the acid present in the mixture, said base having a pKb value above 0.18 and being present in heterogeneous form.
A method for the production of polymers comprising polymerizing a monomer or co-monomer mixture comprising compound (I).
Dependencies are inferred from the claim text.