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US 2010/0249294 A1Published application
Injection molded article and method for the manufacture thereof
AssigneeSabic Innovative Plastics IP B.V.
InventorSean W. Culligan
Life of this patent
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Abstract
The molding defect known as “splay” is reduced in poly(arylene ether) injection molding compositions including specific amounts of poly(arylene ether), rubber-modified polystyrene, triaryl phosphate, and aryl phosphite. The molding compositions are particularly useful for injection molding articles with large, thin sections, such as battery cases for the back-up batteries used in wireless towers.
Claims23
A method of reducing splay in an injection molded article comprising a poly(arylene ether) composition, the method comprising:
- injection molding a poly(arylene ether) composition to form an injection molded article;
- wherein the injection molding comprises filling a barrel of an injection molding machine with the poly(arylene ether) composition and emptying at least 80 weight percent of the barrel to mold a single injection molded article;
- wherein a portion of the injection molded article comprises
- a first dimension of at least 10 centimeters,
- a second dimension of at least 10 centimeters, and
- a third dimension of less than 1 centimeter;
- wherein the poly(arylene ether) composition comprises
- 45 to 65 weight percent of a poly(arylene ether) having an intrinsic viscosity of 0.3 to 0.55 deciliter/gram measured at 25° C. in chloroform,
- 15 to 35 weight percent of a rubber-modified polystyrene, wherein the rubber-modified polystyrene comprises polystyrene and polybutadiene,
- 5 to 25 weight percent of a triaryl phosphate that is a liquid at one atmosphere and at least one temperature in the range 25 to 50° C., and
- 0.1 to 1 weight percent of an aryl phosphite having the structure P(OR1)3, wherein each occurrence of R1 is independently C1-C24 hydrocarbyl, provided that at least one occurrence of R1 is an unsubstituted or substituted C6-C24 aryl.;
- wherein all weight percents are based on the total weight of the poly(arylene ether) composition.
9 more elements
Dependencies are inferred from the claim text.