Method for making silica supported catalysts
OwnerHeiko Morellinventor
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Abstract
A method for making an inorganic oxide supported catalyst involves impregnating an inorganic oxide component with a catalytic metal using an aqueous, acid bath. More specifically, the method involves forming and washing an inorganic oxide component, such as a silica gel or a silica co-gel, for example a silica-zirconia co-gel. The washed inorganic oxide component is then contacted with the acidic bath to effect the impregnation with the catalytic metal, such as cesium, to form an activated inorganic oxide component. Subsequently, the activated component is dried to form the catalyst. The resulting catalysts possess increased surface area, which is beneficial with respect to accessibility and amount of catalytically active sites.
Claims23
A method for making a catalyst comprising forming an inorganic oxide component;
- washing said component;
- contacting said component with an aqueous, acidic bath comprising a catalytic metal to impregnate said component with said catalytic metal to form an activated component;
- and drying said inorganic oxide component to form said catalyst.
The method in accordance with any preceding claim, wherein the aqueous acidic bath is prepared using an acid having a pKa in the range of about 1 to 5.
The method in accordance with any preceding claim, wherein said acidic bath further comprises a salt of said catalytic metal, wherein said catalytic metal is selected from the group consisting of alkali metal and alkaline earth metal.
The method in accordance with any preceding claim, wherein said inorganic oxide component comprises silica.
A method for making a catalyst comprising the steps of:
- combining an alkali metal silicate, a mineral acid, and a source of zirconium to form a hydrosol and allowing said hydrosol to set to form a co-gel;
- washing said co-gel;
- contacting said co-gel with an aqueous, acid bath comprising cesium to impregnate said co-gel with said cesium to form an activated component, wherein said bath has a pH below 7.0 at the end of the metal impregnation;
- and drying said activated component to form said catalyst.
Dependencies are inferred from the claim text.