# US 2010/0168069 A1 · Insect repellent

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- Number: US 2010/0168069 A1
- Document ID: US20100168069A1
- Status: Published application
- Kind: A1
- Application number: 12/377,943
- Filed: 2007-08-17
- Published: 2010-07-01
- Earliest claimed: 2006-08-18
- Inventors: Armand Zurhaar
- Web page: https://patentgrep.com/patent/US20100168069A1

## CPC

- A01N 57/12: containing acyclic or cycloaliphatic radicals
- A01N 57/14: containing aromatic radicals
- A01N: PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF (preservation of food or foodstuff A23); BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES (preparations for medical, dental or toiletry purposes which kill or prevent the growth or proliferation of unwanted organisms A61K); PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS

## Abstract

The invention provides an insect repellent composition that repels flies, gnats, mosquitoes, lice, ticks, and fleas. The insect repellent composition includes an effective amount of a phosphorous containing compound having the formula (RO)3P=Ox or (RO)2P=Ox(OH) alone or in synergistic combination with any one or more compounds selected from a group comprising C10-C20 mono-unsaturated hydrocarbons, optionally substituted C1-C10 alkyl esters, and dicarboxylic acids; wherein R is an optionally substituted C1-C10 alkyl group or aryl or aryl substituted with C1-C10 alkyl or alkoxy; and x is 0 or 1, and a carrier vehicle.

## Claims

### Claim 1

An insect repellent comprising an effective amount of a phosphorous containing compound having the formula (RO)3P=Ox or (RO)2P=Ox(OH) alone or in synergistic combination with at least one a group consisting of: C10-C20 mono-unsaturated hydrocarbons, optionally substituted C1-C10 alkyl esters, and dicarboxylic acids; wherein R is at least one of an optionally substituted C1-C10 alkyl group or aryl or aryl substituted with C1-C10 alkyl and alkoxy; and x is 0 or 1.

### Claim 2 (depends on 1)

The insect repellent according to claim 1, wherein R is selected from a group consisting of: methyl, ethyl, isopropyl, butyl, phenyl and tolyl.

### Claim 3 (depends on 1)

The insect repellent according to claim 1, wherein x is 1.

### Claim 4 (depends on 1)

The insect repellent according to claim 1, comprising triphenyl phosphate alone or in synergistic combination with at least one of a group consisting of: nonadecene, heptadecene, 1,2 benzedicarboxylic acid, and bis (2-methylpropyl) ester.

### Claim 5 (depends on 1)

An insect repellent composition comprising an effective amount of an insect repellent as defined in claim 1 and a carrier vehicle.

### Claim 6 (depends on 5)

The insect repellent composition according to claim 5, wherein the carrier vehicle comprises a liquid.

### Claim 7 (depends on 6)

The insect repellent composition according to claim 6, wherein the insect repellent is miscible or dispersible in a liquid.

### Claim 8 (depends on 6)

The insect repellent composition according to claim 6, wherein the liquid comprises organic solvents selected from a group consisting of liquid saturated hydrocarbons, polar organic solvents, halogenated hydrocarbons, and oils.

### Claim 9 (depends on 5)

The insect repellent composition according to claim 5, wherein the carrier vehicle is selected from a group consisting of gels, oils, dips, pastes, sprays, aerosols, and solid formulations.

### Claim 10 (depends on 5)

The insect repellent composition according to claim 5, further comprising at least one additive.

### Claim 11 (depends on 10)

The insect repellent composition according to claim 10, wherein the at least one additive is selected from a group consisting of a preservative, a colorant, a stabilizer, and a fragrance.

### Claim 12 (depends on 5)

The insect repellent composition according to claim 5, wherein the composition comprises up to 20% of the phosphorous containing compound.

### Claim 13 (depends on 12)

The insect repellent composition according to claim 12, wherein the insect repellent composition comprises triphenyl phosphate (1-6%), nonadecene (0-1%), heptadecene (0-1%), 1,2-benenedicarboxylic acid (0-1%), bis (2-methylpropyl) ester (0-1%) and a carrier vehicle.

### Claim 14 (depends on 12)

The insect repellent composition according to claim 12, wherein the composition comprises about 3-6% w/w triphenylphosphate, 5% w/w eucalyptus oil, 5-10% w/w acetone, 40% w/w linseed oil, 40% w/w liquid hydrocarbon.

### Claim 15

A method comprising:
repelling insects by application of an effective amount of a phosphorous containing compound having the formula (RO)3P=Ox or (RO)2P=Ox(OH) alone or in synergistic combination with at least one compound selected from a group consisting of: C10-C20 mono-unsaturated hydrocarbons, optionally substituted C1-C10 alkyl esters, and dicarboxylic acids; wherein R is selected from a group consisting of an optionally substituted C1-C10 an alkyl group, aryl, an aryl substituted with C1-C10 alkyl and alkoxy; and x is 0 or 1.

### Claim 16

(canceled)

### Claim 17 (depends on 15)

The method according to claim 15 wherein the phosphorous containing compound is topically applied to at least a portion of the area, or at interspersed locations within or on the periphery of the area.

### Claim 18

(canceled)

### Claim 19

An insect repellent comprising an effective amount of a phosphorous containing compound having the formula (RO)3P=Ox or (RO)2P=Ox(OH) wherein R is selected from a group consisting of a C1-C10 alkyl group, an aryl and an aryl substituted with C1-C10 alkyl or alkoxy; and x is 0 or 1.

### Claim 20 (depends on 19)

The insect repellent of claim 19 wherein the phosphorous containing compound is in synergistic combination with at least one a group consisting of: C10-C20 mono-unsaturated hydrocarbons, optionally substituted C1-C10 alkyl esters, and dicarboxylic acids.
