# US 2010/0167369 A1 · Biomass As A Sustainable Energy Source

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- Number: US 2010/0167369 A1
- Document ID: US20100167369A1
- Status: Published application
- Kind: A1
- Application number: 12/515,475
- Filed: 2007-11-20
- Published: 2010-07-01
- Earliest claimed: 2006-11-21
- Inventors: Marco J. Castaldi; Kartik Chandran
- Web page: https://patentgrep.com/patent/US20100167369A1

## CPC

- C10L 3/08: Production of synthetic natural gas
- C01B 3/386: Catalytic partial combustion
- C01B 3/48: followed by reaction of water vapour with carbon monoxide
- C01B 2203/0261: containing a catalytic partial oxidation step [CPO]
- C01B 2203/06: Integration with other chemical processes
- C01B 2203/066: with fuel cells
- C01B 2203/1023: Catalysts in the form of a monolith or honeycomb
- C01B 2203/1058: Nickel catalysts
- C01B 2203/1064: Platinum group metal catalysts
- C01B 2203/84: Energy production
- Y02E 50/30: Fuel from waste, e.g. synthetic alcohol or diesel
- Y02P 20/145: the feedstock being materials of biological origin
- C10L: FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C01B: NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; {METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C}
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

## Abstract

Methods and systems for increasing the generation of methane from a biomass are disclosed. In some embodiments, the method includes the following: decomposing a biomass to produce an gaseous effluent including methane; decomposing a portion of the gaseous effluent in the presence of catalysts to form a decomposed stream including hydrogen, carbon monoxide; converting substantially all of the carbon monoxide in the decomposed stream to carbon dioxide to produce a feed stream including hydrogen and carbon dioxide; and mixing the feed stream with the biomass to facilitate decomposition of the biomass. In some embodiments, the system includes a bioreactor for generating methane from a biomass and additional devices for producing a feed stream including hydrogen and carbon dioxide that is recirculated to the bioreactor to accelerate the production of methane. The additional devices include a catalytic reforming reactor and a shift reactor.

## Claims

### Claim 1

A method of accelerating the production of methane from a biomass, the method comprising:
decomposing a biomass to produce an gaseous effluent including methane;
decomposing a portion of the gaseous effluent in the presence of catalysts to form a decomposed stream including hydrogen, carbon dioxide, and carbon monoxide;
converting substantially all of the carbon monoxide in the decomposed stream to carbon dioxide to produce a feed stream including hydrogen and carbon dioxide; and
mixing the feed stream with the biomass to facilitate decomposition of the biomass.

### Claim 2 (depends on 1)

The method according to claim 1, wherein the biomass is a sanitary wastewater.

### Claim 3 (depends on 1)

The method according to claim 1, further comprising removing liquid from the biomass while it is decomposing.

### Claim 4 (depends on 1)

The method according to claim 1, further comprising mixing air with the gaseous effluent while it is decomposing in the presence of catalysts.

### Claim 5 (depends on 4)

The method according to claim 4, wherein the decomposed stream has an equivalence ratio of 3.0.

### Claim 6 (depends on 1)

The method according to claim 1, further comprising mixing water with the decomposed stream to facilitate production of the feed.

### Claim 7 (depends on 1)

The method according to claim 1, further comprising generating a consumable energy with a portion of the gaseous effluent.

### Claim 8 (depends on 1)

The method according to claim 1, further comprising decomposing the biomass for about 8 to 12 hours.

### Claim 9

A method of accelerating the generation of a consumable energy from a biomass, the method comprising:
decomposing a biomass to produce an gaseous effluent including methane;
decomposing a portion of the gaseous effluent in the presence of catalysts to form a decomposed stream including hydrogen, carbon dioxide, and carbon monoxide;
converting substantially all of the carbon monoxide in the decomposed stream to carbon dioxide to produce a feed stream including hydrogen and carbon dioxide;
mixing the feed stream with the biomass to facilitate decomposition of the biomass;
feeding a portion of the gaseous effluent to a power plant; and
generating a consumable energy with a portion of the gaseous effluent.

### Claim 10 (depends on 9)

The method according to claim 9, further comprising removing liquid from the biomass while it is decomposing.

### Claim 11 (depends on 9)

The method according to claim 9, further comprising mixing air with the gaseous effluent while it is decomposing in the presence of catalysts.

### Claim 12 (depends on 9)

The method according to claim 9, further comprising mixing water with the decomposed stream to facilitate production of the feed.

### Claim 13

A system for accelerating the generation of methane from a biomass, the system comprising:
a bioreactor for decomposing a biomass to produce a gaseous effluent including methane;
a catalytic reforming reactor for decomposing a portion of the gaseous effluent in the presence of catalysts to form a decomposed stream including hydrogen, carbon dioxide, and carbon monoxide;
a shift reactor for converting substantially all of the carbon monoxide in the decomposed stream to carbon dioxide to produce a feed stream including hydrogen and carbon dioxide; and
a conduit from the shift reactor to the bioreactor for directing the feed stream to the bioreactor to facilitate decomposition of the biomass.

### Claim 14 (depends on 13)

The system according to claim 13, wherein the biomass is a sanitary wastewater.

### Claim 15 (depends on 13)

The system according to claim 13, further comprising a means for generating a consumable energy.

### Claim 16 (depends on 15)

The system according to claim 15, wherein the means for generating a consumable energy includes a methane-powered generator.

### Claim 17 (depends on 15)

The system according to claim 15, wherein the means for generating a consumable energy includes a fuel cell.

### Claim 18 (depends on 15)

The system according to claim 15, further comprising a water source for the shift reactor.

### Claim 19 (depends on 15)

The system according to claim 15, further comprising an air source for the catalytic reforming reactor.

### Claim 20 (depends on 17)

The system according to claim 17, further comprising a conduit from the catalytic reforming reactor to the fuel cell for providing hydrogen to the fuel cell.
