# US 2010/0163099 A1 · Solar cell modules comprising encapsulant sheets with low haze and high moisture resistance

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- Number: US 2010/0163099 A1
- Document ID: US20100163099A1
- Status: Published application
- Kind: A1
- Application number: 12/610,435
- Filed: 2009-11-02
- Published: 2010-07-01
- Earliest claimed: 2008-12-31
- Assignees: E. I. Du Pont de Nemours and Company
- Inventors: Richard Allen Hayes; Steven C. Pesek; W Alexander Shaffer; Charles Anthony Smith; Georeg Wyatt Prejean
- Web page: https://patentgrep.com/patent/US20100163099A1

## CPC

- B32B 17/10743: {containing acrylate (co)polymers or salts thereof}
- B32B 17/10853: {the membrane being bag-shaped}
- H10F 19/804: {Materials of encapsulations}
- Y02E 10/50: Photovoltaic [PV] energy
- Y10T 428/1352: Polymer or resin containing [i.e., natural or synthetic]
- Y10T 428/269: including synthetic resin or polymer layer or component
- Y10T 428/31645: Next to addition polymer from unsaturated monomers
- Y10T 428/31855: Of addition polymer from unsaturated monomers
- B32B: LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- H10F: INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

## Abstract

A solar cell module comprising a solar cell layer and an ionomer sheet comprising a sodium/zinc mixed ionomer that is the neutralization product of a precursor acid copolymer; wherein the precursor acid copolymer comprises copolymerized units of an α-olefin having 2 to 10 carbon atoms and about 20 to about 30 wt % of copolymerized units of an α,β-ethylenically unsaturated carboxylic acid having 3 to 8 carbon atoms based on the total weight of the precursor acid copolymer; wherein the precursor acid copolymer has a melt flow rate of about 70 to about 1000 g/10 min, as determined in accordance with ASTM D1238 at 190° C. and 2.16 kg; and wherein when about 40% to about 90% of the total content of the carboxylic acid groups present in the precursor acid copolymer are neutralized to carboxylate groups to comprise carboxylate groups and counterions that consist essentially of sodium ions, the resulting sodium ionomer has a freeze enthalpy that is not detectable or that is less than about 3.0 j/g, when determined by differential scanning calorimetry in accordance with ASTM D3418.

## Claims

### Claim 1

A solar cell module comprising a solar cell layer and an ionomer sheet, wherein,
(A) the solar cell layer comprises a single solar cell or a plurality of electrically interconnected solar cells and;
(B) the ionomer sheet comprises a sodium/zinc mixed ionomer that is the neutralization product of a precursor acid copolymer; wherein the precursor acid copolymer comprises copolymerized units of an α-olefin having 2 to 10 carbon atoms and about 20 to about 30 wt % of copolymerized units of an α,β-ethylenically unsaturated carboxylic acid having 3 to 8 carbon atoms, based on the total weight of the precursor acid copolymer; wherein the precursor acid copolymer has a melt flow rate of about 70 to about 1000 g/10 min, as determined in accordance with ASTM D1238 at 190° C. and 2.16 kg; and wherein said precursor acid copolymer, when neutralized to a level of about 40% to about 90%, based on the total number of the carboxylic acid groups present in the precursor acid copolymer, to comprise carboxylate groups and counterions that consist essentially of sodium ions, produces a sodium ionomer, said sodium ionomer having a freeze enthalpy that is not detectable or that is less than about 3.0 j/g, when determined by differential scanning calorimetry in accordance with ASTM D3418; and wherein said sodium/zinc mixed ionomer comprises carboxylate groups and a mixture of counterions; said mixture of counterions consisting essentially of about 5 to about 95 equivalent % of sodium cations, and, complementarily, about 95 to 5 equivalent % of zinc cations, based on the total number of equivalents of carboxylate groups in the precursor acid copolymer.

### Claim 2 (depends on 1)

The solar cell module of claim 1, wherein the sodium/zinc mixed ionomer is the neutralization product of a precursor acid copolymer that has been neutralized to a level of about 30% to about 90 wt %.

### Claim 3 (depends on 1)

The solar cell module of claim 1, wherein the sodium/zinc mixed ionomer is the neutralization product of a precursor acid copolymer that has been neutralized to a level of about 40% to about 70%.

### Claim 4 (depends on 1)

The solar cell module of claim 1, wherein the sodium/zinc mixed ionomer has a melt flow rate of about 0.7 to about 25 g/10 min or less, when measured according to ASTM D1238 at 190° C. and 2.16 kg.

### Claim 5 (depends on 1)

The solar cell module of claim 1, wherein the precursor acid copolymer comprises about 20 to about 25 wt % of copolymerized units of the α,β-ethylenically unsaturated carboxylic acid.

### Claim 6 (depends on 1)

The solar cell module of claim 1, wherein the mixture of counterions consists essentially of about 50 to about 95 equivalent % of sodium cations, and, complementarily, about 5 to about 50 equivalent % of zinc cations.

### Claim 7 (depends on 1)

The solar cell module of claim 1, wherein the ionomer sheet is in the form of a monolayer sheet and consists essentially of the sodium/zinc mixed ionomer.

### Claim 8 (depends on 1)

The solar cell module of claim 1, wherein the ionomer sheet is in the form of a multilayer sheet and comprises two or more sub-layers, and wherein at least one of the sub-layers consists essentially of the sodium/zinc mixed ionomer and each of the other sub-layer(s) comprises a polymer selected from the group consisting of acid copolymers, ionomers of acid copolymers, poly(ethylene vinyl acetates), poly(vinyl acetals), polyurethanes, polyvinylchlorides, polyethylenes, polyolefin block copolymer elastomers, copolymers of an α-olefin and an α,β-ethylenically unsaturated carboxylic acid ester, silicone elastomers, epoxy resins, and combinations of two or more thereof.

### Claim 9 (depends on 1)

The solar cell module of claim 1, wherein the ionomer sheet has a total thickness of about 1 to about 120 mils (about 0.025 to about 3 mm).

### Claim 10 (depends on 1)

The solar cell module of claim 1, wherein the ionomer sheet is directly laminated to the solar cell layer.

### Claim 11 (depends on 1)

The solar cell module of claim 1, wherein the solar cell layer has a front sun-facing side and a back non-sun-facing side.

### Claim 12 (depends on 11)

The solar cell module of claim 11, which comprises a front encapsulant layer laminated to the front sun-facing side of the solar cell layer and a back encapsulant layer laminated to the back non-sun-facing side of the solar cell layer, wherein one of the front and back encapsulant layers is the ionomer sheet and the other of the front and back encapsulant layers comprises a polymeric material selected from the group consisting of acid copolymers, ionomers of acid copolymers, poly(ethylene vinyl acetates), poly(vinyl acetals), polyurethanes, polyvinylchlorides, polyethylenes, polyolefin block copolymer elastomers, copolymers of an α-olefin and an α,β-ethylenically unsaturated carboxylic acid ester, silicone elastomers, epoxy resins, and combinations thereof.

### Claim 13 (depends on 12)

The solar cell module of claim 12, which comprises two ionomer sheets, wherein each of the front and back encapsulant layers comprises one of the two ionomer sheets.

### Claim 14 (depends on 11)

The solar cell module of claim 11, further comprising an incident layer, wherein the incident layer is an outermost surface layer of the module and is positioned to the front sun-facing side of the solar cell layer.

### Claim 15 (depends on 11)

The solar cell module of claim 11, further comprising a backing layer, wherein the backing layer is an outermost surface layer of the module and is positioned to the back non-light receiving side of the solar cell layer.

### Claim 16 (depends on 14)

The solar cell module of claim 14, wherein the incident layer is selected from the group consisting of (i) glass sheets, (ii) polymeric sheets comprising a polymer selected from the group consisting of polycarbonates, acrylics, polyacrylates, cyclic polyolefins, polystyrenes, polyamides, polyesters, fluoropolymers, and combinations of two or more thereof, and (iii) polymeric films comprising a polymer selected from the group consisting of polyesters, polycarbonates, polyolefins, norbornene polymers, polystyrenes, styrene-acrylate copolymers, acrylonitrile-styrene copolymers, polysulfones, nylons, polyurethanes, acrylics, cellulose acetates, cellophanes, silicones, poly(vinyl chlorides), fluoropolymers, and combinations of two or more thereof.

### Claim 17 (depends on 15)

The solar cell module of claim 15, wherein the backing layer is selected from the group consisting of (i) glass sheets, (ii) polymeric sheets, (iii) polymeric films, (iv) metal sheets, and (v) ceramic plates, and wherein the polymeric sheets comprise a polymer selected from the group consisting of polycarbonates, acrylics, polyacrylates, cyclic polyolefins, polystyrenes, polyamides, polyesters, fluoropolymers, and combinations or two or more thereof; and the polymeric films comprise a polymer selected from the group consisting of polyesters, polycarbonates, polyolefins, norbornene polymers, polystyrenes, styrene-acrylate copolymers, acrylonitrile-styrene copolymers, polysulfones, nylons, polyurethanes, acrylics, cellulose acetates, cellophanes, poly(vinyl chlorides), fluoropolymers, and combinations of two or more thereof.

### Claim 18 (depends on 11)

The solar cell module of claim 11, wherein the solar cells are wafer-based solar cells selected from the group consisting of crystalline silicon and multi-crystalline silicone based solar cells.

### Claim 19 (depends on 18)

The solar cell module of claim 18, which consists essentially of, in order of position, (i) an incident layer, (ii) a front encapsulant layer laminated to the front sun-facing side of the solar cell layer, (iii) the solar cell layer, (iv) a back encapsulant layer laminated to the back non-sun-facing side of the solar cell layer, and (v) a backing layer, wherein one of the front and back encapsulant layers is the ionomer sheet.

### Claim 20 (depends on 19)

The solar cell module of claim 19, which comprises two of the ionomer sheets, wherein each of the front and back encapsulant layers comprises one of the two ionomer sheets.

### Claim 21 (depends on 11)

The solar cell module of claim 11, wherein the solar cells are thin film solar cells selected from the group consisting of amorphous silicon, microcrystalline silicon, cadmium telluride, copper indium selenide, copper indium/gallium diselenide, light absorbing dyes, and organic semiconductors based solar cells.

### Claim 22 (depends on 21)

The solar cell module of claim 21, which consists essentially of, in order of position, (i) an incident layer, (ii) a front encapsulant layer comprising the ionomer sheet, and (iii) the solar cell layer, wherein the solar cell layer further comprises a substrate upon which the thin film solar cells are deposited and the substrate is positioned such that the substrate is an outermost surface of the module and is positioned on the back non-sun-facing side of the solar cell layer.

### Claim 23 (depends on 21)

The solar cell module of claim 21, which consists essentially of, in order of position (i) the solar cell layer, (ii) a back encapsulant layer comprising the ionomer sheet, and (iii) a backing layer, wherein the solar cell layer further comprises a superstrate upon which the thin film solar cells are deposited and the superstrate is positioned such that the superstrate is an outermost surface of the module on the front sun-facing side of the solar cell layer.

### Claim 24 (depends on 1)

A process for preparing a solar cell module, comprising: (i) providing an assembly comprising all the component layers recited in claim 1 and (ii) laminating the assembly to form the solar cell module.

### Claim 25 (depends on 24)

The process of claim 24, wherein the laminating step is conducted by subjecting the assembly to heat and optionally vacuum or pressure.