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US 2010/0160883 A1Published application
Highly swellable absorption medium with reduced caking tendency
AssigneeStockhausen GmbH & Co. KG
InventorsGerd Jonas, Richard Mertens, Markus Frank
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Abstract
The present invention concerns highly swellable absorption mediums with a reduced caking tendency at high humidity and/or high temperatures, wherein a swellable polymer is coated with a non-ionic, nitrogen-containing surfactant and optionally a Lewis acid and then reacted by heating.
Claims7
A process for the production of an absorption medium with a reduced caking tendency in a moist environment and/or at high temperatures, comprising the steps of:
- providing a component I which is a water- or aqueous fluid-absorbing, dried, surface-cross-linked polymer particle based on polymerized monomers containing at least partially neutralized acid groups;
- surface coating component I with a coating agent selected from the group consisting of nitrogen-containing, non-ionic surfactants as component II and optionally a Lewis acid as component III;
- and heat-treating the mixture, wherein said surfactant has the general formula I:
- in which
- R1 is an aliphatic C1 to C30 hydrocarbon z-substituted aliphatic residue,
- R2 is selected from a hydrogen, an C2 to C24 aliphatic hydrocarbon residue, and a hydroxyalkylene residue
- R3, which may be identical or different, has the same meaning as R2, provided that with amide compounds, at least one of residues R2 or R3 represents a hydroxyalkylene residue or an alkoxylated hydroxyalkylene residue or a corresponding esterified or alkoxylated or esterified and alkoxylated hydroxyalkylene residue with the definition given for R2 above;
- n is 1;
- and z is a whole number from 1 to 4.
6 more elements
Dependencies are inferred from the claim text.