Orthogonally fixed compounds for electrooptical applications
AssigneeTechnische Universität Braunschweig
InventorsHans-Hermann Johannes, Wolfgang Kowalsky, Martin Dümeland, Ulfla Wrenz
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Abstract
The present invention relates to chemical compounds that can be used in electrooptical applications. The electrically conductive and optical properties of these compounds, e.g. hole transporting, electron transporting and/or light emitting properties can be predetermined by substituting the core structure of these compounds with respective residues. The core structure (1) of the compounds according to the invention comprises two opposing aromatic moieties which are chemically bonded through an intermediate central atom. This central atom has a tetraedric configuration and therefore provides an orthogonal orientation to the organic moieties.
Claims14
Compound useful for electronic and/or electrooptic devices, characterized by a core structure of formula I:
- wherein V, W, X and Y are selected from at least divalent atoms or groups,
- wherein at least one of V, W and X, Y, respectively, is no chemical bond but an at least divalent atom or group,
- wherein R3 to R14 are independently selected from (hetero-) alkyls, (hetero-) aryls,
- —NR′2, —OR′, —SR′, —CN, —F, —CF3, with R′ independently selected from substituted or unsubstituted (hetero-)alkyl, (hetero-)aryl or hydrogen, and electrooptically functional groups,
- wherein A3 to A14 are independently carbon or nitrogen atoms and
- wherein Z is a central tetraedric atom.
Compound according to one of the preceding claims, characterized in that two or more of R3 to R14 are condensed arenyl groups or are groups forming a higher condensed analog of the core structure of formula I.
Compound according to one of the preceding claims, characterized in that central tetraedric atom Z is selected from the group comprising silicon, germanium and carbon.
Compound according to one of the preceding claims, characterized in that least one of R3 to R14 is selected from hole transporting residues, electron transporting residues and emitter residues.
Compound useful for electronic and/or electrooptic devices, represented by one of the following formulae:
Compound according to one of the preceding claims, characterized in that the compound is a hole transporter, electron transporter and/or emitter.
Process for synthesis of compounds useful for electroluminescent devices, characterized by generating a compound according to one of the preceding claims.
Dependencies are inferred from the claim text.