Aqueous compositions comprising a blend of emulsion copolymers
AssigneeRohm and Haas Company
InventorsZhenwen Fu, Andrew Hejl, Aurelia C. Sheppard, Andrew J. Swartz
Life of this patent
Estimating the term…
Abstract
The present invention provides compositions that enable excellent early hardness development in coating applications, the compositions comprising a blend of one or more acrylic emulsion copolymer, pA, having a Tg of 20° C. or higher, and one or more acrylic emulsion copolymer, pB, having a Tg at least 15° C. lower than that of pA, together with one or more additive chosen from a coalescent having a normal boiling point no greater than 300° C., a naturally derived plasticizer, and mixtures thereof. The compositions may be ambient curable.
Claims11
An aqueous composition comprising:
- a. a plurality of polymer particles (A) comprising one or more copolymer, pA, having weight average molecular weight greater than 100,000 and a glass transition temperature, Tg, of 20° C. or higher, as measured by differential scanning calorimetry, DSC;
- b. a plurality of polymer particles (B) comprising one or more copolymer, pB, having weight average molecular weight greater than 5,000 and a glass transition temperature, Tg, as measured by differential scanning calorimetry, DSC, at least 15° C. lower than the Tg of pA;
- and
- c. one or more additive to improve film formation chosen from:
- a coalescent having a normal boiling point no greater than 300° C. present in an amount of at least 4%, based on the total weight of solids of the copolymers pA and pB, a naturally derived plasticizer present in an amount of at least 0.5%, based on the total weight of solids of the copolymers pA and pB, and mixtures thereof;
- wherein the weight ratio of the copolymer solids of pA to the copolymer solids of pB is from 65/35 to 90/10, and
- further wherein said composition, when dried under ambient conditions, forms a film upon evaporation of water.
Dependencies are inferred from the claim text.