Workability of an aqueous formulation with a hydraulic binder base using a combination of comb-branched polymers
AssigneeCoatex
InventorsDavid Platel, Jean Moro, Olivier Guerret
Life of this patent
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Abstract
The invention pertains to improving the workability of an aqueous formulation with a hydraulic binder base using a combination between at least one comb-branched copolymer having a (meth)acrylic skeleton, onto which are grafted side-chains terminated by a hydrophilic group, and at least one comb-branched copolymer having a (meth)acrylic skeleton, onto which are grafted side-chains terminated by a hydrophobic group.
Claims23
1- A method of improving the workability of an aqueous formulation, the method comprising adding a hydraulic binder base to the aqueous formulation, wherein the hydraulic binder base comprises:
- a) at least one comb-branched (meth)acrylic copolymer having at least one side-chain bearing at least one alkoxy-polyalkylene glycol and hydroxy-polyalkylene glycol hydrophilic group, and
- b) at least one comb-branched (meth)acrylic copolymer having at least one side-chain bearing at least one alkoxy-polyalkylene glycol and hydroxy-polyalkylene glycol hydrophobic group.
2- The method according to claim 1, wherein said comb-branched copolymer a) and said comb-branched copolymer b) are added separately into said aqueous formulation.
3- The method according to claim 1, wherein said comb-branched copolymer a) and said comb-branched copolymer b) are added in the form of a mixture.
4- The method according to claim 3, wherein the mixture has a dry material content of from 20% and 40% of its total weight.
5- The method according to claim 3, wherein the mixture has a dry solids content of comb-branched copolymer a) of from 5% and 95% of its total solid matter.
The method according to claim 3, wherein the mixture has a dry solids content of comb-branched copolymer a) of from 10% and 90% of its total solid matter.
7- The method according to claim 1, wherein said comb-branched copolymer a) comprises, expressed as a percentage by weight of each of its monomers, the sum of those percentages being equal to 100%:
- a1) 5% to 30% of (meth)acrylic acid,
- a2) 70% to 95% of at least one monomer having the formula (I):
- where:
- m, n, p and q are whole numbers and m, n, p are less than 150, q is greater than 0, and at least one whole number of m, n and p is not 0;
- R is a radical that includes a polymerizable unsaturated function;
- R1 and R2 are identical or different, and represent hydrogen or alkyl,
- R′ represents hydrogen or a hydrocarbon radical having 1 to 3 carbons, or an ionic or ionizable group,
- a3) 0% to 50% of at least one monomer different from monomers a1) and a2), and which is selected from the group consisting of an ester, an amide, an ether, a styrenic monomer, a cationic monomer, a sulfonated monomer, a phosphated monomer.
The method according to claim 7, wherein a3) is ethyl acrylate.
The method according to claim 7, wherein R′ represents an ionic or ionizable group selected from the group consisting of a phosphate, a phosphonate, a sulfate, a sulfonate, a carboxylic, a primary amine, a secondary amine, a tertiary amine, a quaternary ammonium, and a mixture thereof.
10- The method according to claim 1, wherein said comb-branched copolymer b) comprises, expressed as a percentage by weight of each of its monomers, the sum of those percentages being equal to 100%:
- b1) 30% to 95% of (meth)acrylic acid,
- b2) 5% to 70% of at least one monomer having the formula (I):
- (I)
- where:
- m, n, p and q are whole numbers and m, n, p are less than 150, q is greater than 0, and at least one whole number of m, n and p is not 0;
- R is a radical that includes a polymerizable unsaturated function;
- R1 and R2 are identical or different, and represent hydrogen or alkyl,
- R′ represents a hydrocarbon radical having 8 to 36 carbon atoms,
- b3) 0% to 50% of at least one monomer different from monomers a1) and a2) selected from the group consisting of an ester, an amide, an ether, a styrenic monomer, a cationic monomer, a sulfonated monomer, and a phosphated monomer.
The method according to claim 10, wherein b3) is ethyl acrylate.
12- The method according to claim 1, wherein said formulation is a cement, a mortar, a concrete, or a grout.
The method according to claim 1, wherein said formulation is a cement.
14- The method according to claim 1, wherein said aqueous formulation with a hydraulic binder base contains 0.1% to 2% solids content of components a) and b) in relation to the solid content of the hydraulic binder.
15- An aqueous formulation, comprising a hydraulic binder base and
- a) at least one comb-branched (meth)acrylic copolymer having at least one side-chain bearing at least one alkoxy- or hydroxy-polyalkylene glycol hydrophilic group,
- b) at least one comb-branched (meth)acrylic copolymer having at least one side-chain bearing at least one alkoxy- or hydroxy-polyalkylene glycol hydrophobic group.
The formulation according to claim 15, wherein said comb-branched copolymer a) comprises, expressed as a percentage by weight of each of its monomers, the sum of those percentages being equal to 100%:
- a1) 5% to 30% of (meth)acrylic acid,
- a2) 70% to 95% of at least one monomer having the formula (I):
- where:
- m, n, p and q are whole numbers and m, n, p are less than 150, q is greater than 0, and at least one whole number of m, n and p is not 0;
- R is a radical that includes a polymerizable unsaturated function;
- R1 and R2 are identical or different, and represent hydrogen or alkyl,
- R′ represents hydrogen or a hydrocarbon radical having 1 to 3, or an ionic or ionizable group,
- a3) 0% to 50% of at least one monomer different from monomers a1) and a2), and which is selected from the group consisting of an ester, an amide, an ether, a styrenic monomer, a cationic monomer, a sulfonated monomer, and a phosphated monomer.
The formulation according to 16, wherein R′ represents an ionic or ionizable group selected from the group consisting of a phosphate, a phosphonate, a sulfate, a sulfonate, a carboxylic, a primary amine, a secondary amine, a tertiary amine, a quaternary ammonium, and a mixture thereof.
The formulation according to claim 15, wherein said comb-branched copolymer b) comprises, expressed as a percentage by weight of each of its monomers, the sum of those percentages being equal to 100%:
- b1) 30% to 95% of (meth)acrylic acid,
- b2) 5% to 70% of at least one monomer having the formula (I):
- where:
- m, n, p and q are whole numbers and m, n, p are less than 150, q is greater than 0, and at least one whole number of m, n and p is not 0;
- R is a radical that includes a polymerizable unsaturated function;
- R1 and R2 are identical or different, and represent hydrogen or alkyl,
- R′ represents a hydrocarbon radical having 8 to 36 carbon atoms,
- b3) 0% to 50% of at least one monomer different from monomers a1) and a2), and which is selected from the group consisting of an ester, an amide, an ether, a styrenic monomer, a cationic monomer, a sulfonated monomer, and a phosphated monomer.
21- The formulation according to claim 15, wherein said formulation is a cement, a mortar, a concrete, or a grout
The formulation according to claim 15, wherein said formulation is a concrete.
23- The formulation according to claim 15, comprising 0.1% to 2% solids content of components a) and b) in relation to the solid content of the hydraulic binder.
Dependencies are inferred from the claim text.