# US 2010/0121128 A1 · Method and apparatus for thermochemical conversion of materials

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- Number: US 2010/0121128 A1
- Document ID: US20100121128A1
- Status: Published application
- Kind: A1
- Application number: 11/407,770
- Filed: 2006-04-19
- Published: 2010-05-13
- Earliest claimed: 2006-04-19
- Inventors: Robert L. Hance; John E. Kane; Stephanie G. Dye
- Web page: https://patentgrep.com/patent/US20100121128A1

## CPC

- F23G 7/003: {for used articles}
- F23G 2203/504: with essentially horizontal flow of bed material
- F23G 2900/50804: using thermit or other compositions of metal oxides as auxiliary fuel
- Y02E 20/12: Heat utilisation in combustion or incineration of waste
- F23G: CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

A system for treating carbon-containing or silicon-containing end-of-life material includes a reactor 10 for simultaneously supporting oxidation of the waste material and conversion of CO2 within the reactor. A metal oxide or metal is input to the reactor to convert the CO2 to a mineralized CO2 product. A cold trap 44 is provided for capturing exhaust gases from the reactor and returning condensate to the reactor, and a pump 50 maintains a desired vacuum or pressure within the reactor and the cold trap.

## Claims

### Claim at position 1

1-14. (canceled)

### Claim 15

A method for treating a carbon-containing waste material, comprising:
supporting simultaneous oxidation of the waste material and conversion to CO2 in a reaction chamber of a reactor;
simultaneously with said oxidation and conversion, inputting a metal oxide or metal to the reaction chamber to convert the CO2 to a mineral product;
capturing exhaust gases from the reaction chamber;
returning at least a portion of the captured exhaust gases to the reaction chamber; and
maintaining a desired pressure within the reaction chamber.

### Claim 16 (depends on 15)

A method as defined in claim 15, further comprising:
inputting fuel to the reactor; and
inputting a reaction gas or vapor to the reactor.

### Claim 17 (depends on 16)

A method as defined in claim 16, wherein the fuel and the reaction gases input to the reactor generate a reaction temperature of at least about 300° C. and less than about 900° C.

### Claim 18

(canceled)

### Claim 19 (depends on 15)

A method as defined in claim 15, wherein the reactor is a fluid bed reactor that rotates about a substantially horizontal reactor axis; and
the reactor has a reaction chamber volume of from 20 to 2,000 liters.

### Claim 20 (depends on 15)

A method as defined in claim 15, wherein reaction of the CO2 with the metal oxide or metal produces a mineral carbonate.

### Claim 21 (depends on 15)

A method as defined in claim 15, wherein the metal or metal oxide includes a metal from a group consisting of calcium, magnesium, aluminum, sodium, cadmium, manganese, lead, nickel, chromium, uranium, magnesium, beryllium and barium.

### Claim 22 (depends on 15)

A method as described in claim 15, wherein energy produced by the reaction is used to generate power or provide heat.

### Claim 23

A method for treating a carbon-containing waste material, comprising:
supporting simultaneous oxidation of the waste material and conversion to CO2 in a reaction chamber of a fluid bed reactor that rotates about a substantially horizontal axis;
simultaneously with said oxidation and conversion, inputting a metal oxide or metal to the reaction chamber to convert the CO2 to a mineral product;
capturing exhaust gases from the reaction chamber; and
returning at least a portion of the captured exhaust gases to the reaction chamber; and
maintaining a desired pressure within the fluid bed reactor.

### Claim 24 (depends on 23)

A method as defined in claim 23, further comprising:
inputting fuel to the fluid bed reactor; and
inputting a reaction gas or vapor to the reactor.

### Claim 25 (depends on 23)

A method as defined in claim 23, wherein the fuel and the reaction gases input to the reactor generate a reaction temperature of at least about 300° C. and less than about 900° C.

### Claim 26 (depends on 23)

A method as defined in claim 23, wherein reaction of the CO2 with the metal oxide or metal produces a mineral carbonate.

### Claim 27 (depends on 23)

A method as defined in claim 23, wherein the metal or metal oxide includes a metal from a group consisting of calcium, magnesium, aluminum, sodium, cadmium, manganese, lead, nickel, chromium, uranium, magnesium, beryllium and barium.

### Claim 28 (depends on 23)

A method as described in claim 23, wherein energy produced by the reaction is used to generate power or provide heat.

### Claim 29

A method for treating a carbon-containing waste material to generate power or provide heat, comprising:
supporting simultaneous oxidation of the waste material and conversion to CO2 in a reaction chamber of a reactor;
simultaneously with said oxidation and conversion, inputting a metal oxide or metal to the reaction chamber to convert the CO2 to a mineral carbonate;
inputting a reaction gas or vapor to the reaction chamber;
capturing exhaust gases from the reaction chamber and returning at least a portion of the exhaust gases to the reaction chamber; and
maintaining a desired pressure within the reaction chamber.

### Claim 30 (depends on 29)

A method as defined in claim 29, wherein the fuel and the reaction gases input to the reactor generate a reaction temperature of at least about 300° C. and less than about 900° C.

### Claim 31 (depends on 29)

A method as defined in claim 29, further comprising:
converting condensable vapors in the captured exhaust gases to a condensate, and returning at least some of the condensate to the reactor.

### Claim 32 (depends on 29)

A method as defined in claim 29, wherein the reactor is a fluid bed reactor that rotates about a substantially horizontal reactor axis.

### Claim 33 (depends on 29)

A method as defined in claim 29, wherein the metal or metal oxide includes a metal from a group consisting of calcium, magnesium, aluminum, sodium, cadmium, manganese, lead, nickel, chromium, uranium, magnesium, beryllium and barium.
