New polyisocyanate mixtures, a process for their preparation and their use in coating compositions

Abstract

The present invention relates to polyacrylate-modified polyisocyanates which are i) prepared from aromatic, araliphatic, cycloaliphatic and/or aliphatic polyisocyanates having an NCO content of 5% to 25% by weight, an NCO functionality ≧2, a viscosity measured as solvent free resin of 150 to 200,000 mPa·s at 23° C., and ii) contain at least one structural unit of the formula (I) wherein R is hydrogen or a methyl group, R1 is an optionally heteroatom-containing hydrocarbon radical and R2 is a hydrocarbon radical having at least one isocyanate group and optionally urethane, allophanate, biuret, uretdione, isocyanurate and/or iminooxadiazinedione groups and n is a number ≧1. The present invention also relates to a process for preparing these polyisocyanates and to binder compositions containing these polyisocyanates, which may be hydrophilically modified, and a compound having NCO-reactive groups.

Dependencies are inferred from the claim text.