Polyester synthesis
AssigneeXerox Corporation
InventorJordan H. Wosnick
Life of this patent
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Abstract
The present disclosure provides methods for modifying polymeric resin materials after polymerization to make fine adjustments in the chemical or physical properties of the resin, or in modifying the structure of the polymer chains. The resulting resins may be useful in forming toner particles. In embodiments, a polymeric resin may have epoxy groups added to its backbone to increase its melting point. The resulting polymer, sometimes referred to herein as an epoxidized polymer, may, in turn, be reacted with wax-like components, to increase the compatibility of the polyester with waxes utilized in forming toner particles. In other embodiments, the resulting epoxidized polymer may be reacted with components possessing carboxylic acid groups to adjust the acid value and weight average molecular weight of the resin.
Claims20
A process comprising:
- contacting at least one unsaturated polyester with at least one epoxidizing agent selected from the group consisting of peroxyacids, peroxyphthalates, hydrogen peroxide with a suitable catalyst, and combinations thereof to form an epoxidized polyester resin;
- contacting the epoxidized polyester resin with at least one colorant, an optional wax, and an optional surfactant to form toner particles;
- and
- recovering the toner particles.
A process comprising:
- contacting at least one unsaturated polyester with at least one epoxidizing agent selected from the group consisting of peroxyacids, peroxyphthalates, hydrogen peroxide and a suitable catalyst, and combinations thereof to form an epoxidized polyester resin;
- contacting the epoxidized polyester resin with a component selected from the group consisting of wax-like components and components possessing carboxylic acid groups to form a modified epoxidized polyester resin;
- contacting the modified epoxidized polyester resin with at least one colorant, an optional wax, and an optional surfactant to form toner particles;
- and
- recovering the toner particles.
A toner comprising:
- an epoxidized polyester resin optionally in combination with at least one other resin selected from the group consisting of amorphous polyester resins and crystalline polyester resins;
- and
- one or more optional ingredients selected from the group consisting of colorants, waxes, and combinations thereof.
Dependencies are inferred from the claim text.