Dispersion strengthened L12 aluminum alloys
AssigneeUnited Technologies Corporation
InventorAwadh B. Pandey
Life of this patent
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Abstract
An improved L12 aluminum alloy having magnesium or nickel; at least one of scandium, erbium, thulium, ytterbium, and lutetium; at least one of gadolinium, yttrium, zirconium, titanium, hafnium, and niobium; and at least one ceramic reinforcement. Aluminum oxide, silicon carbide, aluminum nitride, titanium boride, titanium diboride and titanium carbide are suitable ceramic reinforcement particles. These alloys derive strengthening from mechanisms based on dislocation-particle interaction and load transfer to stiffen reinforcements.
Claims22
An aluminum alloy having high strength, ductility and toughness, comprising:
- at least one metal selected from the group comprising:
- about 1 to about 8 weight percent magnesium and about 1 to about 10 weight percent nickel;
- at least one first element selected from the group comprising:
- about 0.1 to about 0.5 weight percent scandium, about 0.1 to about 6 weight percent erbium, about 0.1 to about 10 weight percent thulium, about 0.1 to about 15 weight percent ytterbium, and about 0.1 to about 12 weight percent lutetium;
- at least one second element selected from the group comprising:
- about 0.1 to about 4 weight percent gadolinium, about 0.1 to about 4 weight percent yttrium, about 0.05 to about 1 weight percent zirconium, about 0.05 to about 2 weight percent titanium, about 0.05 to about 2 weight percent hafnium, and about 0.05 to 1 weight percent niobium;
- at least one ceramic selected from the group comprising:
- about 5 to about 40 volume percent aluminum oxide, about 5 to about 40 volume percent silicon carbide, about 5 to about 40 volume percent aluminum nitride, about 5 to 40 volume percent titanium diboride, about 5 to about 40 volume percent titanium boride, and about 5 to about 40 volume percent titanium carbide;
- and
- the balance substantially aluminum.
A heat treatable aluminum alloy comprising:
- at least one metal selected from about 1 to about 8 weight percent magnesium and about 1 to about 10 weight percent nickel;
- an aluminum solid solution matrix containing a plurality of dispersed Al3X second phases having L12 structures where X comprises at least one of scandium, erbium, thulium, ytterbium, lutetium, and at least one of gadolinium, yttrium, zirconium, titanium, hafnium, niobium;
- and
- at least one ceramic selected from the group comprising:
- about 5 to about 40 volume percent aluminum oxide, about 5 to about 40 volume percent silicon carbide, about 5 to about 40 volume percent aluminum nitride, about 5 to about 40 volume percent titanium diboride, about 5 to about 40 volume percent titanium boride, and about 5 to about 40 volume percent titanium carbide;
- and
- the balance substantially aluminum.
A method of forming an aluminum alloy having high strength, ductility and toughness, the method comprising:
- (a) forming an alloy powder comprising:
- at least one metal selected from the group comprising:
- about 1 to about 8 weight percent of magnesium and about 1 to about 10 weight percent of nickel;
- at least one first element selected from the group comprising:
- about 0.1 to about 0.5 weight percent scandium, about 0.1 to about 6 weight percent erbium, about 0.1 to about 10 weight percent thulium, about 0.1 to about 15 weight percent ytterbium, and about 0.1 to about 12 weight percent lutetium;
- at least one second element selected from the group comprising:
- about 0.1 to about 4 weight percent gadolinium, about 0.1 to about 4 weight percent yttrium, about 0.05 to about 1 weight percent zirconium, about 0.05 to about 2 weight percent titanium, about 0.05 to about 2 weight percent hafnium, and about 0.05 to about 1 weight percent niobium;
- and
- the balance substantially aluminum;
- (b) adding at least one ceramic selected from the group comprising:
- about 5 to about 40 volume percent aluminum oxide, about 5 to about 40 volume percent silicon carbide, about 5 to about 40 volume percent aluminum nitride, about 5 to about 40 volume percent titanium diboride, about 5 to about 40 volume percent titanium boride, and about 5 to about 40 volume percent titanium carbide;
- and
- (c) consolidating the powder and ceramic to form the alloy.
Dependencies are inferred from the claim text.