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US 2009/0256111 A1Published application
Dialkylborane amine complexes
AssigneeBASF Aktiengesellschaft Patents, Trademarks and Licenses
InventorElizabeth Burkhardt
Life of this patent
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Abstract
The present invention relates to new dialkylborane amine complexes, a process for the synthesis of new dialkylborane amine complexes, solutions comprising new dialkylborane amine complexes and a method of using new dialkylborane amine complexes for organic reactions.
Claims15
1-10. (canceled)
A dialkylborane amine complex of the formula (1)
- (R1)2BH•amine (1),
- wherein
- R1 is C1—C10 alkyl, C3—C10 cycloalkyl, C6—C14 aryl, C7—C16 aralkyl, C7—C16 alkaryl, C2—C10 alkenyl, C2—C10 alkynyl, substituted C1—C10 alkyl, CH2SiMe3, isopinocampheyl, or the two R1 groups together with the BH moiety connecting them are 9-borabicyclo[3.3.1]nonane, boracyclopentane, 3-methyl-1-boracyclopentane or 3,4-dimethyl-1-boracyclopentane, and
- amine represents quinoline, quinoxaline or a substituted pyridine of the formula (2)
- wherein
- R2 is methyl, ethyl, propyl, isopropyl, n-butyl, isobutyl, sec-butyl, amyl, isoamyl, sec-amyl, 1,2-dimethylpropyl, n-hexyl, 4-methylpentyl, 1-methylpentyl, 2-methylpentyl, 3-methylpentyl, 2,2-dimethylbutyl, 3,3-dimethylbutyl, 1,2-dimethylbutyl, 1,3-dimethylbutyl, 1,2,2-trimethylpropyl, n-heptyl, 5-methylhexyl, 1-methylhexyl, 2,2-dimethylpentyl, 3,3-dimethylpentyl, 4,4-dimethylpentyl, 1,2-dimethylpentyl, 1,3-dimethylpentyl, 1,4-dimethylpentyl, 1,2,3-trimethylbutyl, 2-ethylhexyl, n-octyl, 6-methylheptyl, 1-methylheptyl, n-nonyl, 1-, 2-, 3-, 4-, 5-, 6- or 7-methyloctyl, 1-, 2-, 3-, 4- or 5-ethylheptyl, 1-, 2- or 3-propylhexyl, n-decyl, 1-, 2-, 3-, 4-, 5-, 6-, 7- or 8-methylnonyl, 1-, 2-, 3-, 4-, 5- or 6-ethyloctyl, 1-, 2-, 3- or 4-propylheptyl, C1—C8 alkoxy or C1—C8-alkoxy-C1—C10 alkyl, and
- R3 is hydrogen or a C1—C10 alkyl, C1—C8 alkoxy or C, —C8-alkoxy-C1—C10 alkyl group, which is not bound to the 6-position of the pyridine ring,
- with the provision that R3 is not hydrogen and the amine in (1) is not quinoline when the dialkylborane is 9-borabicyclo[3.3.1]nonane.
5 more elements
A process to synthesize the new dialkylborane amine complexes according to claim 1, comprising the step of reacting a dialkylborane (R1)2BH with the amine.
Dependencies are inferred from the claim text.