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US 2009/0189086 A1Published application
Use of aryl-or alkyloxy-substituted phthalocyanines as marking substances for liquids
AssigneeBASF SE
InventorsThomas Gessner, Sophia Ebert, Rüdiger Sens, Martin Könemann, Wolfgang Ahlers, Christos Vamvakaris
Life of this patent
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Abstract
Phthalocyanines of the formula (I) where the symbols and indices each have the definitions specified in the description are suitable as markers for liquids, especially mineral oils.
Claims14
1-13. (canceled)
A method for marking a liquid, comprising the step of adding to the liquid as a marker a phthalocyanine of the formula (I)
- where the symbols and indices in the formula (I) have the following definitions:
- M is twice hydrogen, twice lithium, magnesium, zinc, copper, nickel, VO, TiO, AlCl, AlOCOCH3, AlOCOCF3, SiCl2 or Si(OH)2;
- m is 1, 2, 3 or 4;
- n is the same or different and is 0, 1, 2, 3 or 4;
- r is the same or different and is 0, 1, 2, 3 or 4;
- m+r is 1, 2, 3 or 4;
- n+r is 0, 1, 2, 3 or 4;
- R is the same or different and is
- R1 is the same or different and is H, halogen or R2;
- R2 is the same or different and is (C1-C18)-alkyl, (C4-C8)-cycloalkyl, (C2-C12)-alkenyl, (C8-C10)-aryl, (C7-C20)-aralkyl or (C2-C12)-alkynyl, where aryl radicals are unsubstituted or substituted by one or more halogen, cyano, nitro, hydroxyl, amino, C1-C20-alkyl which is optionally interrupted by from 1 to 4 oxygen atoms in ether function, C1-C20-alkoxy, C1-C20-alkylamino or C1-C20-dialkylamino;
- R3 is the same or different and is R1, or two R3 radicals or one R1 radical and one R3 radical together form a further ring system;
- R4, R5, R6 are the same or different and are each H, halogen, CH3 or C2H5;
- Y1, Y2, Y3, Y4, Y5, Y6 are the same or different and are each (C1-C4)-alkylene which is unsubstituted or substituted by one or more halogen atoms;
- s is 0, 1, 2, 3, 4, 5, or 6;
- and
- t is 0, 1, 2, 3.
13 more elements
Dependencies are inferred from the claim text.