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US 2009/0176972 A1Published application
Novel reactive dyestuff with N,N-dialkylamino bridge group
AssigneeEverlight USA, Inc.
InventorsWen-Jang Chen, Ya-Cing Yu, Hong-Chang Huang, Chien-Yu Chen, Chen-Lung Kao, Hsien-Chung Hsia
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Abstract
The present invention relates to a novel reactive dyestuff with an N,N-dialkylamino bridge group, represented by the following formula (I): wherein R, B, B′, E1, E2, Z, Z′, i, j, R1, R2, m and n are defined the same as the specification. The reactive dyestuff of the present invention is suitable for exhaust dyeing, cold batch-up dyeing, continuous dyeing, printing and digital spray printing materials that contain hydroxyl group or polyamine fibers.
Claims21
A reactive dyestuff with an N,N-dialkylamino bridge group of the following formula (I),
- wherein, E1 and E2 each independently are couplers selected from the group consisting of benzene, naphthalene, pyrazolone, monoazo, disazo, polyazo and metal complex azo components;
- R is hydrogen, C1-4 alkyl, C1-4 alkylcarbonyl, phenyl, nitroso or C1-4 alkyl substituted by halogen, hydroxyl, carboxyl or sulfo;
- (R1)0-3 and (R2)0-3 each independently are 0 to 3 identical or different groups, and each of R1 and R2 independently is selected from the group consisting of hydrogen, halogen, hydroxyl, carboxyl, sulfo, nitro, cyano, C1-4 alkyl, C1-4 alkoxy, ureido and amido;
- B and B′ each independently are selected from the group consisting of a direct bond, —SO2— and —CONH—(CH2)k—SO2—;
- k is an integer between 1 to 6;
- Z and Z′ each independently are selected from the group consisting of —SO2—U, —CONH—(CH2)d—SO2—U, —O—(CH2)r—CONH—(CH2)d—SO2—U, β-thiosulfatoethylsulfonyl and —N(R′)—U′;
- d and r are integers independent of one another between 2 to 4;
- U is —CH2CH2W or —CH═CH2;
- W is a leaving group, selecting from the group consisting of —Cl, —OSO3H and —OPO3H, which is eliminable by a base, a quaternary salt selected from the group consisting of quaternary ammonium, pyridine, carboxypyridinium, methylpyridinium and carbonamidopyridinium, or a group of
- R3 and R4 each independently are hydrogen or C1-4 alkyl;
- U′ is α,β-halopropionyl, α-haloacryloyl, β-halopropionyl or α-haloacryloyl;
- R′ is hydrogen or C1-4 alkyl;
- i and j are integers independent of one another between 0 to 2, and the sum of i and j is not 0;
- and
- m and n are integers independent of one another between 2 to 4.
12 more elements
Dependencies are inferred from the claim text.