Process for synthetic lubricant production
AssigneeExxonMobil Research and Engineering Company
InventorsAbhimanyu Onkar Patil, Satish Bodige
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Abstract
A process for the preparation of oligomeric poly alpha-olefins comprises oligomerizing low molecular weight PAO in the presence of an ionic liquid catalyst under oligomerization conditions. The low molecular weight PAOs used as a feed or feed component of the present process are the light olefinic by-product fraction including the dimers and light fractions from the metallocene-catalyzed PAO oligomerization process.
Claims25
A process for the preparation of oligomeric poly alpha-olefins which comprises oligomerizing in the presence of an acidic ionic liquid oligomerization catalyst a low molecular weight PAO produced by the metallocene-catalyzed oligomerization of an alpha-olefin feed.
A process for the preparation of oligomeric poly alpha-olefins which comprises co-oligomerizing in the presence of an acidic ionic liquid oligomerization catalyst system, (i) a C40— olefinic fraction derived from the a low molecular weight PAO produced by the metallocene-catalyzed oligomerization of a C8 to C14 alpha-olefin feed and comprising a mixture having a molecular weight in the range of 120 to 600, of C8H16 to C30H60 oligomers of the alpha-olefin feed, and containing a terminal olefin content of at least 50% of total olefinic unsaturation, (ii) a C8 to C14 alpha-olefin, the ionic liquid catalyst system comprising an aluminum halide or alkyl aluminum halide and a quaternary ammonium, quaternary phosphonium, or tertiary sulfonium ionic liquid compound.
A process for the preparation of oligomeric poly alpha-olefins in the lube oil boiling range which comprises oligomerizing, in the presence of an acidic ionic liquid oligomerization catalyst, a low molecular weight olefinic feed which comprises at least 25% of vinylidene compounds of the formula:
- R1R2 C═CH2
- where R1 and R2, which may be the same or different, together have from 6 to 40 carbon atoms and R1 is a hydrocarbon group of 1 to 24 carbon atoms, R2 is R1 or H.
Dependencies are inferred from the claim text.