Photosensitive polymer, resist composition, and associated methods
AssigneeCheil Industries Inc.
InventorsSang-Jun Choi, Youn-Jin Cho, Seung-Wook Shin, Hye-Won Kim
Life of this patent
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Abstract
A photosensitive polymer, the photosensitive polymer including repeating units represented by Formulae 1 to 3: wherein R1 and R3 are independently hydrogen or methyl, R2 is a C4 to C20 acid-labile group, R4 is a lactone-derived group, AR is a substituted or unsubstituted phenyl ring, or a substituted or unsubstituted aryl having from two to three fused aromatic rings, carbon CAR is bonded directly to an aromatic ring of AR, l, m, and n are positive integers, 1/(l+m+n) is about 0.1 to about 0.5, m/(l+m+n) is about 0.3 to about 0.5, and n/(l+m+n) is about 0.1 to 0.4.
Claims15
A photosensitive polymer, the photosensitive polymer including repeating units represented by Formulae 1 to 3:
- wherein, in Formulae 1 to 3:
- R1 and R3 are independently hydrogen or methyl,
- R2 is a C4 to C20 acid-labile group,
- R4 is a lactone-derived group,
- AR is a substituted or unsubstituted phenyl ring, or a substituted or unsubstituted aryl having from two to three fused aromatic rings,
- carbon CAR is bonded directly to an aromatic ring of AR,
- l, m, and n are positive integers,
- 1/(l+m+n) is about 0.1 to about 0.5,
- m/(l+m+n) is about 0.3 to about 0.5, and
- n/(l+m+n) is about 0.1 to 0.4.
A method of patterning a material, the method comprising:
- forming a resist layer on the material;
- forming a resist pattern from the resist layer using a lithographic process;
- and
- patterning the material through the resist pattern, wherein:
- the resist layer includes a photosensitive polymer, the photosensitive polymer including repeating units represented by Formulae 1 to 3:
- and, in Formulae 1 to 3:
- R1 and R3 are independently hydrogen or methyl,
- R2 is a C4 to C20 acid-labile group,
- R4 is a lactone-derived group,
- AR is a substituted or unsubstituted phenyl ring, or a substituted or unsubstituted aryl having from two to three fused aromatic rings,
- carbon CAR is bonded directly to an aromatic ring of AR,
- l, m, and n are positive integers,
- 1/(l+m+n) is about 0.1 to about 0.5,
- m/(l+m+n) is about 0.3 to about 0.5, and
- n/(l+m+n) is about 0.1 to 0.4.
Dependencies are inferred from the claim text.