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US 2009/0076199 A1Published application
Red dye mixture
AssigneeLANXESS Deutschland GmbH
InventorsStephan Michaelis, Horst Berneth, Eberhard Kuckert
Life of this patent
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Abstract
Mixtures have been found comprising at least one red dye of the formula (I), (C) or (CI) and at least one orange dye of the formula (L), (LI), (LII), (LIII), (LIV) or (LV) where the substituents have the definition in the description, these mixtures being suitable more particularly for the mass colouring of plastics.
Claims31
Mixtures comprising at least one red dye of formulae (I), (C) or (CI)
- wherein
- R1 is hydrogen, unsubstituted or substituted C1-C8-alkyl or unsubstituted or substituted C3-C8-cycloalkyl,
- B is a bridge of the formulae —O—B1—O— or —CH2—B2—CH2—,
- B1 is a bridge of the formula
- B2 is a bridge of the formula
- R2 is hydrogen, methyl, ethyl, methoxy or fluorine,
- X is a bridge of the formula
- Y is a bridge of the formula
- l is an integer from 0 to 8,
- m, n, p and r independently of one another are an integer from 1 to 8,
- q is an integer from 2 to 8 and
- s and t independently of one another are an integer from 1 to 4,
- R20 and R22 independently of one another are cyano or optionally substituted C1-C8-alkoxycarbonyl,
- R21 is hydrogen or optionally substituted C1-C3-alkyl
- R23 is hydrogen, unsubstituted or substituted C1-C8-alkyl or unsubstituted or substituted C1-C8-alkoxycarbonyl,
- R24 is cyano, unsubstituted or substituted C1-C8-alkylsulphonyl or unsubstituted or substituted C1-C8-alkoxycarbonyl,
- R25 is unsubstituted or substituted C1-C8-alkyl, unsubstituted or substituted C3-C7-cycloalkyl, unsubstituted or substituted C6-C10-aryl,
- R26 is hydrogen or independently of R25 has the definition of R25, or
- NR25R26 is pyrrolidino, piperidino or morpholino,
- R27 is one or more radicals having the definition hydrogen, unsubstituted or substituted C1-C8-alkyl, unsubstituted or substituted C1-C8-alkoxy, fluorine, cyano, unsubstituted or substituted C3-C7-cycloalkyl or unsubstituted or substituted C6-C10-aryl,
- R28 is hydrogen or unsubstituted or substituted C1-C8-alkyl,
- and at least one orange dye of the formula (L), (LI), (LII), (LIII), (LIV) or (LV)
- in which
- R10 is hydrogen, unsubstituted or substituted C1-C8-alkyl, unsubstituted or substituted C1-C8-alkoxy, unsubstituted or substituted C1-C8-alkylsulphonyl unsubstituted or substituted C1-C8-alkoxycarbonyl nitro, cyano or fluorine,
- R11 is hydrogen, unsubstituted or substituted C1-C8-alkyl, unsubstituted or substituted C1-C8alkoxy, optionally substituted C1-C8-alkoxycarbonyl, nitro, cyano or fluorine,
- R12 is hydrogen, unsubstituted or substituted C1-C8-alkyl or unsubstituted or substituted C3-C8-cycloalkyl,
- R13 is hydrogen, unsubstituted or substituted C1-C8-alkyl or unsubstituted or substituted C1-C8-alkoxycarbonyl,
- R14 is cyano, unsubstituted or substituted C1-C8-alkylsulphonyl or unsubstituted or substituted C1-C8-alkoxycarbonyl,
- X1 is O or S,
- X2 is N or C—CN,
- R15 and R16 independently of one another are unsubstituted or substituted C1-C8-alkyl, unsubstituted or substituted C3-C8-cycloalkyl or unsubstituted or y substituted C6-C10-aryl, or
- NR15R16 is pyrrolidino, piperidino or morpholino,
- R17 is hydrogen or C1-C8-alkyl,
- R18 is unsubstituted or substituted C6-C10-aryl,
- R23′ is hydrogen, unsubstituted or substituted C1-C8-alkyl or unsubstituted or substituted C1-C8-alkoxycarbonyl,
- R24′ is cyano, unsubstituted or substituted C1-C8-alkylsulphonyl or unsubstituted or substituted C1-C8-alkoxycarbonyl,
- R25′ is unsubstituted or substituted C1-C8-alkyl, optionally substituted C3-C7-cycloalkyl, unsubstituted or substituted C6-C10-aryl,
- R26′ is hydrogen or independently of R25′ has the definition of R25′, or
- NR25′R26′ is pyrrolidino, piperidino or morpholino,
- R43 and R44 independently of one another are hydrogen, unsubstituted or substituted C1-C4-alkyl, nitro, cyano, C1-C4-alkoxycarbonyl, and
- R45 is hydrogen, methyl, fluorine or chlorine.
38 more elements
A compound of the formula I
- in which
- —B— is —O—B1—O— or —CH2—B2—CH2—,
- R1 is hydrogen, optionally substituted C1-C8-alkyl or unsubstituted or substituted C3-C8-cycloalkyl,
- B1 is a bridge of the formula
- B2 is a bridge of the formula
- R2 is methyl, ethyl methoxy or fluorine,
- X is a bridge of the formula
- Y is a bridge of the formula
- l is an integer from 0 to 8,
- m, n, p and r independently of one another are an integer from 1 to 8,
- q is an integer from 2 to 8 and
- s and t independently of one another are an integer from 1 to 4.
9 more elements
The compound of the formula
- wherein
- —B— is —O—B1—O— or —CH2—B2—CH2—,
- R1 is hydrogen, optionally substituted C1-C8-alkyl or unsubstituted or substituted C3-C8-cycloalkyl,
- B1 is a bridge of the formula
- B2 is a bridge of the formula
- R2 is methyl, ethyl, methoxy or fluorine,
- X is a bridge of the formula
- Y is a bridge of the formula
- l is an integer from 0 to 8,
- m, n, p and r independently of one another are an integer from 1 to 8,
- q is an integer from 2 to 8 and
- s and t independently of one another are an integer from 1 to 4.
9 more elements
Dependencies are inferred from the claim text.