Polyvinyl alcohol having 1,2-glycol bond in side chain and process for preparing the same
AssigneeThe Nippon Synthetic Chemical Industry Co., Ltd.
InventorMitsuo Shibutani
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Abstract
There is disclosed a polyvinyl alcohol having a 1,2-glycol bond in a side chain, which has the features that there is no generation of dimethyl carbonate in the preparation thereof, no need of an eliminating process of dimethyl carbonate in the recovering process of waste liquid after hydrolysis. Also, even an introduction amount of 1,2-glycol bonds is increased, there is no deterioration of solubility in a hydrolyzing solution (methanol) of a copolymer (paste) before hydrolysis, further, water-insoluble is not lowered even in experiencing thermal history. Specifically, there is provided a polyvinyl alcohol having a 1,2-glycol bond in a side chain obtained by hydrolyzing a copolymer of a vinyl ester monomer and a compound shown in the formula (1).
Claims8
A polyvinyl alcohol having a 1,2-glycol bond in a side chain obtained by hydrolyzing a copolymer of a vinyl ester monomer and a compound shown in the following formula (1):
- (wherein R1 is a hydrogen atom or an alkyl group, R2 is a single bond or an alkylene group having 1 to 3 carbon atoms, which may have an alkyl group, each of R3 and R4 are independently a hydrogen atom or R5—CO— (wherein R5 is an alkyl group)).
A process for preparing a polyvinyl alcohol having a 1,2-glycol bond in a side chain, wherein a copolymer of a vinyl ester monomer and a compound shown in the formula (1) is hydrolyzed.
Dependencies are inferred from the claim text.