# US 2008/0187691 A1 · Rapid Ink Drying Papers

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- Number: US 2008/0187691 A1
- Document ID: US20080187691A1
- Status: Published application
- Kind: A1
- Application number: 11/672,156
- Filed: 2007-02-07
- Published: 2008-08-07
- Earliest claimed: 2007-02-07
- Assignees: S.D. Warren Company
- Inventors: Alonzo K. Osgood; Steven L. Masia; Daniel R. Coughlin; Phillip S. Coleman
- Web page: https://patentgrep.com/patent/US20080187691A1

## CPC

- D21H 19/82: superposed {(D21H19/84 takes precedence)}
- D21H: PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR

## Abstract

Papers are provided which exhibit rapid ink setting and ink drying. These papers include a topcoat layer, and a penultimate coating layer that draws ink through the topcoat layer. In some implementations, the penultimate coating layer includes a high internal pore volume filler, and/or has a fine external pigment pore structure.

## Claims

### Claim 1

A paper comprising:
a basesheet;
a penultimate coating layer; and
a porous topcoat disposed directly adjacent the penultimate coating layer and having a surface exposed to receive a printed image;
wherein the penultimate coating layer is configured to draw ink vehicle through the topcoat.

### Claim 2 (depends on 1)

The paper of claim 1 wherein the penultimate coating includes a filler having a high internal pore volume.

### Claim 3 (depends on 1)

The paper of claim 1 wherein the penultimate coating layer has an external pigment pore structure with a peak mean pore diameter finer than 0.20 μm.

### Claim 4 (depends on 3)

The paper of claim 3 wherein the penultimate coating layer has an external pigment pore structure with a peak mean pore diameter finer than 0.10 μm.

### Claim 5 (depends on 2)

The paper of claim 2 wherein the penultimate coating layer includes up to 30% of said filler.

### Claim 6 (depends on 2)

The paper of claim 2 wherein the filler is selected from the group consisting of synthetic amorphous silica gels, synthetic calcium silicate, synthetic silicon dioxide, calcined clay, porous calcium carbonate, and mixtures thereof.

### Claim 7 (depends on 2)

The paper of claim 2 wherein the filler comprises a particulate material that creates micro-spores in the coating by interaction of the particulate material with itself or other materials in the coating.

### Claim 8 (depends on 2)

The paper of claim 2 wherein the filler has an internal pore volume of at least 0.8 ml/gram.

### Claim 9 (depends on 1)

The paper of claim 1 wherein the penultimate coating layer comprises a pigment or pigment blend having an overall particle size distribution such that about 25% of the particles are finer than 0.2 μm, about 50% of the particles are finer than 0.5 μm, and about 70% of the particles are finer than 2 μm.

### Claim 10 (depends on 9)

The paper of claim 9 wherein the penultimate coating layer comprises a blend of pigments having different particle size distributions, the pigments being selected and provided in relative proportions so as to provide the overall particle size distribution.

### Claim 11 (depends on 1)

The paper of claim 1 wherein the penultimate coating layer includes a component having high ink vehicle interactivity.

### Claim 12 (depends on 1)

The paper of claim 1 wherein the topcoat comprises a pigment or pigment blend having an overall particle size distribution such that about 20% of the particles are finer than 0.2 μm, about 60% of the particles are finer than 0.5 μm, and 95% of the particles are finer than 2 μm.

### Claim 13 (depends on 12)

The paper of claim 12 wherein the topcoat comprises a blend of pigments having different particle size distributions, the pigments being selected and provided in relative proportions so as to provide the overall particle size distribution.

### Claim 14 (depends on 1)

The paper of claim 1 wherein the topcoat has an external pigment pore structure with a peak mean pore diameter finer than about 0.12 μm.

### Claim 15 (depends on 14)

The paper of claim 14 wherein the topcoat has an external pigment pore structure with a peak mean pore diameter finer than about 0.10 μm.

### Claim 16 (depends on 1)

The paper of claim 1 wherein the topcoat is substantially free of absorbent materials.

### Claim 17

A paper comprising:
a basesheet;
a penultimate coating layer comprising (a) a filler having a high internal pore volume; and (b) a pigment or pigment blend having an overall particle size distribution such that about 25% of the particles are finer than 0.2 μm, about 50% of the particles are finer than 0.5 μm, and about 70% of the particles are finer than 2 μm; and
a porous topcoat, disposed directly adjacent the penultimate coating layer and having a surface exposed to receive a printed image.

### Claim 18 (depends on 17)

The paper of claim 17 wherein the penultimate coating further comprises a component having high ink vehicle interactivity.

### Claim 19 (depends on 17)

The paper of claim 17 wherein the penultimate coating layer has an external pigment pore structure with a peak mean pore diameter finer than 0.20 μm.

### Claim 20 (depends on 17)

The paper of claim 17 wherein the topcoat has an external pigment pore structure with a peak mean pore diameter finer than about 0.12 μm.

### Claim 21 (depends on 20)

The paper of claim 20 wherein the topcoat has an external pigment pore structure with a peak mean pore diameter finer than about 0.10 μm.

### Claim 22 (depends on 17)

The paper of claim 17 wherein the topcoat is substantially free of absorbent materials.
