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US 2008/0075951 A1Published application
Fluoroacrylates and hardcoat compositions including the same
Assignee3M Innovative Properties Company
InventorsZai-Ming Qiu, Naiyong Jing
Life of this patent
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Abstract
Fluoroacrylate additives and hardcoat compositions including the same. The hardcoats can be particularly useful as a hardcoat layer on protective films or optical displays. Methods of forming the hardcoat layer from the hardcoat composition.
Claims22
A hardcoat composition comprising:
- i) at least one non-fluorinated crosslinking agent, and
- ii) at least one fluoroacrylate having the formula:
- Rf3-J-OC(O)NH—K—HNC(O)O—(CbH2b)CH(3-v)((CyH2y)OC(O)C(R8)═CH2)v
- wherein, Rf3 is a monovalent perfluoroalkyl group or a polyfluoroalkyl group which can be linear, branched, or cyclic;
- J is a divalent linkage group selected from:
- —SO2-N(R)—ChH2h—, —C(O)—N(R)—ChH2h—, —(CH2)h—, —O(CH2)h—, —(CH2)h—O—(CH2)j—, or —(CH2)h—S—(CH2)j—;
- wherein R is H or an alkyl group of 1 to 4 carbon atoms;
- h is 2 to 8;
- j is 1 to 5;
- K is the residue of a diisocyanate with an unbranched symmetric alkylene group, arylene group, or aralkylene group;
- b is 1 to 30;
- v is 1 to 3;
- y is 0 to 6;
- and
- R8 is H, CH3, or F;
- and
- iii) at least one initiator.
14 more elements
Dependencies are inferred from the claim text.