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US 2007/0191585 A1Published application
Organic polymer film and method for forming the same
OwnerNobuo Aoiinventor
Life of this patent
Estimating the term…
Abstract
A method for forming an organic polymer film includes a step of polymerizing a monomer including an adamantane derivative in which a substituent group having a carbon number of 1 or more, a functional group or a functional group bonded to a substituent group is bonded to at least the 1-, 3-, 5- and 7-positions of an adamantane skeleton.
Claims10
A method for forming an organic polymer film comprising a step of copolymerizing one or plural kinds of first monomer and one or plural kinds of second monomer,
- said first monomer including a carboxylic acid derivative having an adamantane skeleton represented by the following Chemical Formula 1 and determined in accordance with selection of X1, X2, X3 and X4 in Chemical Formula 1:
- wherein each of X1, X2, X3 and X4 is one selected from the group consisting of a substituent group represented by the following Chemical Formula 2, a substituent group represented by the following Chemical Formula 3, a hydrogen atom, an aliphatic group and an aromatic group, and at least one of X1, X2, X3 and X4 is said substituent group represented by Chemical Formula 2 or said substituted group represented by Chemical Formula 3:
- said second monomer including an amine derivative having an adamantane skeleton represented by the following Chemical Formula 4 and determined in accordance with selection of Y1, Y2, Y3 and Y4 in Chemical Formula 4:
- Chemical Formula 4:
- wherein each of Y1, Y2, Y3 and Y4 is one selected from the group consisting of substituent groups respectively represented by the following Chemical Formula 5, 6, 7, 8, 9, 10, 11 and 12, a hydrogen atom, an aliphatic group and an aromatic group, and at least one of Y1, Y2, Y3 and Y4 is one of said substituent groups respectively represented by Chemical Formula 5, 6, 7, 8, 9, 10, 11 and 12:
2 more elements
A method for forming an organic polymer film comprising the steps of:
- applying a solution on a substrate, said solution including one or plural kinds of first monomer and one or plural kinds of second monomer;
- and
- copolymerizing, through backing, said one or plural kinds of first monomer and said one or plural kinds of second monomer included in said solution applied on said substrate,
- said first monomer including a carboxylic acid derivative having an adamantane skeleton represented by the following Chemical Formula 13 and determined in accordance with selection of X1, X2, X3 and X4 in Chemical Formula 13:
- wherein each of X1, X2, X3 and X4 is one selected from the group consisting of a substituent group represented by the following Chemical Formula 14, a substituent group represented by the following Chemical Formula 15, a hydrogen atom, an aliphatic group and an aromatic group, and at least one of X1, X2, X3 and X4 is said substituent group represented by Chemical Formula 14 or said substituted group represented by Chemical Formula 15:
- said second monomer including an amine derivative having an adamantane skeleton represented by the following Chemical Formula 16 and determined in accordance with selection of Y1, Y2, Y3 and Y4 in Chemical Formula 16:
- wherein each of Y1, Y2, Y3 and Y4 is one selected from the group consisting of substituent groups respectively represented by the following Chemical Formula 17, 18, 19, 20, 21, 22, 23 and 24, a hydrogen atom, an aliphatic group and an aromatic group, and at least one of Y1, Y2, Y3 and Y4 is one of said substituent groups respectively represented by Chemical Formula 17, 18, 19, 20, 21, 22, 23 and 24:
4 more elements
An organic polymer film comprising a polymer of one or plural kinds of first monomer and one or plural kinds of second monomer,
- said first monomer including a carboxylic acid derivative having an adamantane skeleton represented by the following Chemical Formula 25 and determined in accordance with selection of X1, X2, X3 and X4 in Chemical Formula 25:
- wherein each of X1, X2, X3 and X4 is one selected from the group consisting of a substituent group represented by the following Chemical Formula 26, a substituent group represented by the following Chemical Formula 27, a hydrogen atom, an aliphatic group and an aromatic group, and at least one of X1, X2, X3 and X4 is said substituent group represented by Chemical Formula 26 or said substituted group represented by Chemical Formula 27:
- said second monomer including an amine derivative having an adamantane skeleton represented by the following Chemical Formula 28 and determined in accordance with selection of Y1, Y2, Y3 and Y4 in Chemical Formula 28:
- wherein each of Y1, Y2, Y3 and Y4 is one selected from the group consisting of substituent groups respectively represented by the following Chemical Formula 29, 30, 31, 32, 33, 34, 35 and 36, a hydrogen atom, an aliphatic group and an aromatic group, and at least one of Y1, Y2, Y3 and Y4 is one of said substituent groups respectively represented by Chemical Formula 29, 30, 31, 32, 33, 34, 35 and 36:
1 more element
A method for forming an organic polymer film comprising a step of copolymerizing a first monomer and a second monomer,
- wherein in the step of copolymerizing a first monomer and a second monomer, said first monomer is a monomer including an adamantane derivative in which a substituent group having a carbon number of 1 or more, a functional group or a functional group bonded to a substituent group is bonded to at least three positions out of the 1-, 3-, 5- and 7-positions of an adamantane skeleton, at least one of functional groups is a carboxyl group, and a substituent group bonded to a functional group is an aromatic group, and
- said second monomer is a monomer including an adamantane derivative in which a substituent group having a carbon number of 1 or more, a functional group or a functional group bonded to a substituent group is bonded to at least three positions out of the 1-, 3-, 5- and 7-positions of an adamantane skeleton, at least one of functional groups is a hydroxyl group, and a substituent group bonded to a functional group is an aromatic group.
The method for forming an organic polymer film of claim 8,
- wherein said first monomer includes a carboxylic acid derivative having an adamantane skeleton represented by the following Chemical Formula 37:
- wherein each of X1, X2, X3 and X4 is one selected from the group consisting of a substituent group represented by the following Chemical Formula 38, a substituent group represented by the following Chemical Formula 39, a hydrogen atom, an aliphatic group and an aromatic group, and at least one of X1, X2, X3 and X4 is said substituent group represented by Chemical Formula 38 or said substituted group represented by Chemical Formula 39:
- said second monomer includes an amine derivative having an adamantane skeleton represented by the following Chemical Formula 40:
- wherein each of Y1, Y2, Y3 and Y4 is one selected from the group consisting of substituent groups respectively represented by the following Chemical Formula 41, 42, 43, 44, 45, 46, 47 and 48, a hydrogen atom, an aliphatic group and an aromatic group, and at least one of Y1, Y2, Y3 and Y4 is one of said substituent groups respectively represented by Chemical Formula 41, 42, 43, 44, 45, 46, 47 and 48:
- and
- one or plural kinds of first monomer determined in accordance with selection of said X1, X2, X3 and X4 and one or plural kinds of second monomer determined in accordance with selection of said Y1, Y2, Y3 and Y4 are copolymerized in the step of copolymerizing a first monomer and a second monomer.
3 more elements
An organic polymer film comprising a copolymer of a first monomer and a second monomer,
- wherein said first monomer is a monomer including an adamantane derivative in which a substituent group having a carbon number of 1 or more, a functional group or a functional group bonded to a substituent group is bonded to at least three positions out of the 1-, 3-, 5- and 7-positions of an adamantane skeleton, at least one of functional groups is a carboxyl group, and a substituent group bonded to a functional group is an aromatic group, and
- said second monomer is a monomer including an adamantane derivative in which a substituent group having a carbon number of 1 or more, a functional group or a functional group bonded to a substituent group is bonded to at least three positions out of the 1-, 3-, 5- and 7-positions of an adamantane skeleton, at least one of functional groups is a hydroxyl group, and a substituent group bonded to a functional group is an aromatic group.
Dependencies are inferred from the claim text.