US 2007/0191562 A1 · Composition comprising a monomer compound exhibiting an optical property, method making use of said composition, a monomer compound, a polymer containing said monomer compound and the use thereof

Abstract

The invention relates to a cosmetic or pharmaceutical composition comprising, in a physiologically acceptable medium, at least one type of polymer containing at least one type of novel monomer compound exhibiting optical properties. Said invention also relates to a cosmetic method for making up or treating keratinous materials, in particular a body or face skin, lips, nails, eyebrows, eyelashes and/or hairs, including the application of said cosmetic composition to said materials. Novel monomer compounds exhibiting optical properties, polymers containing said compounds and the use thereof in a composition in order to transfer the optical properties thereto, in particular fluorescent properties are also disclosed.

Claims56

Dependent claims

A cosmetic or pharmaceutical composition comprising, in a physiologically acceptable medium, at least one polymer comprising at least one monomeric compound of formula (I):

in which:
R2 and R3, which are present on the same ring or each on a different ring, represent, independently of each other, a hydrogen, a halogen or a group of formula —X-G-P (II), with the proviso that at least one of the radicals R2 and/or R3 represents a group of formula (II), in which:
X is chosen from the groups —O—, —S—, —SO—, —SO2—, —NH— and —NR— with R representing a linear, branched and/or cyclic, saturated and/or unsaturated carbon-based radical containing 1 to 30 carbon atoms, optionally substituted with one or more groups chosen from ═O, OH, NH2 and halogen atoms;
and/or optionally interrupted with one or more heteroatoms chosen from O, N, P, Si and S;
G is a linear, branched and/or cyclic, saturated and/or unsaturated divalent carbon-based radical containing 1 to 32 carbon atoms, optionally substituted with one or more groups chosen from ═O, OH, NH2 and halogen atoms;
and/or optionally interrupted with one or more heteroatoms chosen from O, N, P, Si and S;
P is a polymerizable group chosen from one of the following formulae:
in which:
R′ represents H or a linear or branched, saturated C1-6 hydrocarbon-based radical,
X′ represents O, NH or NR″ with R″ representing a radical chosen from C1-6 alkyl, C6-10 aryl, (C6-10)aryl(Cl-6)alkyl and (C1-6)alkyl(C6-10)aryl radicals, the alkyl and/or aryl groups also possibly being substituted with one or more groups chosen from OH, halogen, C1-6 alkoxy and C6-10 aryloxy;
preferably, X′ represents O;
m is equal to 0 or 1;
n is equal to 0 or 1;
p is equal to 0, 1 or 2;
and
B represents one of the following divalent aromatic groups (IVa) to (IVd):
in which:
R1 is linear, branched and/or cyclic, saturated and/or unsaturated carbon-based radical containing 1 to 32 carbon atoms, optionally substituted with one or more groups chosen from ═O, OH, NH2 and halogen atoms;
and/or optionally interrupted with one or more heteroatoms chosen from O, N, P, Si and S;
R22 is a hydrogen atom or a linear, branched and/or cyclic, saturated and/or unsaturated carbon-based radical containing 1 to 32 carbon atoms, optionally substituted with one or more groups chosen from ═O, OH, NH2 and halogen atoms;
and/or optionally interrupted with one or more heteroatoms chosen from O, N, P, Si and S;
R20 and R21 are, independently of each other, a hydrogen atom, a linear or branched C1-8 alkyl radical or a cyclopentyl, cyclohexyl, cyclooctyl, cyclodecyl, cyclododecyl, benzyl, naphthyl or phenyl radical.

19 more elements

The composition as claimed in either of claims 14 and 12, in which the polymer is a statistical, alternating, grafted, block or gradient copolymer.

A monomeric compound of formula (I):

in which:
R2 and R3, present on the same ring or each on a different ring, represent, independently of each other, a hydrogen, a halogen or a group of formula —X-G-P (II), with the proviso that at least one of the radicals R2 and/or R3 represents a group of formula (II), in which:
X is chosen from —O—, —S—, —SO—, —SO2—, —NH— and —NR— groups with R representing a linear, branched and/or cyclic, saturated and/or unsaturated carbon-based radical containing 1 to 30 carbon atoms, optionally substituted with one or more groups chosen from ═O, OH, NH2 and halogen atoms;
and/or optionally interrupted with one or more heteroatoms chosen from O, N, P, Si and S;
G is a linear, branched and/or cyclic, saturated and/or unsaturated divalent carbon-based radical, containing 1 to 32 carbon atoms, optionally substituted with one or more groups chosen from ═O, OH, NH2 and halogen atoms;
and/or optionally interrupted with one or more heteroatoms chosen from O, N, P, Si and S;
P is a polymerizable group chosen from one of the following formulae:
in which:
R′ represents H or a linear or branched, saturated C1-6 hydrocarbon-based radical,
X′ represents O, NH or NR″ with R″ representing a radical chosen from C1-6 alkyl, C6-10 aryl, (C6-10)aryl(C1-6)alkyl and (C1-6)alkyl(C6-10)aryl radicals, the alkyl and/or aryl groups also possibly being substituted with one or more groups chosen from OH, halogen, C1-6 alkoxy and C6-10 aryloxy;
preferably, X′ represents O;
m is equal to 0 or 1;
n is equal to 0 or 1;
p is equal to 0, 1 or 2;
and
B represents one of the following divalent aromatic groups (IVa) to (IVd):
in which:
R1 is a linear, branched and/or cyclic, saturated and/or unsaturated carbon-based radical containing 1 to 32 carbon atoms, optionally substituted with one or more groups chosen from ═O, OH, NH2 and halogen atoms;
R22 is a hydrogen atom or a linear, branched and/or cyclic, saturated and/or unsaturated carbon-based radical containing 1 to 32 carbon atoms, optionally substituted with one or more groups chosen from ═O, OH, NH2 and halogen atoms;
and/or optionally interrupted with one or more heteroatoms chosen from O, N, P, Si and S;
R20 and R21 are, independently of each other, a hydrogen atom, a linear or branched C1-8 alkyl radical or a cyclopentyl, cyclohexyl, cyclooctyl, cyclodecyl, cyclododecyl, benzyl, naphthyl or phenyl radical;
with the exclusion of the compounds for which, simultaneously, P is of formula (IIIa), X′ is O, m=1, X is NH and B is of formula (IVc).

19 more elements

Dependencies are inferred from the claim text.

Composition comprising a monomer compound exhibiting an optical property, method making use of said composition, a monomer compound, a polymer containing said monomer compound and the use thereof

Life of this patent

Composition comprising a monomer compound exhibiting an optical property, method making use of said composition, a monomer compound, a polymer containing said monomer compound and the use thereof

Life of this patent

Abstract

Claims56