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US 2007/0191554 A1Published application
Curable fluoropolyether compositions and integral molded resin/rubber articles
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsHiromasa YAMAGUCHI, Mikio Shiono
Life of this patent
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Abstract
Curable fluoropolyether compositions comprising (a) a polyfluorodialkenyl compound, (b) a fluorinated organohydrogenpolysiloxane, (c) a platinum catalyst, (d) hydrophobic silica powder, and (e) a tackifier in the form of a specific silicon compound cure to thermoplastic resins to form a tight bond within a short time and are readily releasable from metal molds.
Claims11
A curable fluoropolyether composition comprising
- (a) 100 parts by weight of a polyfluorodialkenyl compound having at least two alkenyl groups per molecule,
- (b) a fluorinated organohydrogenpolysiloxane having at least two silicon-bonded hydrogen atoms (i.e., SiH groups) per molecule in a sufficient amount to provide 0.5 to 5.0 moles of SiH groups per mole of alkenyl groups available from component (a),
- (c) a platinum group compound in an amount to provide 0.1 to 500 ppm of platinum group metal based on the total weight of components (a) and (b),
- (d) 5 to 50 parts by weight of hydrophobic silica powder, and
- (e) 0.01 to 30 parts by weight of a tackifier in the form of at least one silicon compound selected from the general formulae (I), (II), and (III):
- A-(D-B)x-D-A (I)
- C—(B-D)x-B—C (II)
- A-E (III)
- wherein A and B each are a silane or siloxane linkage having at least one silicon-bonded hydrogen atom and optionally a silicon-bonded substituent group, said substituent group, if present, is an unsubstituted hydrocarbon group of 1 to 20 carbon atoms or a monovalent organic group of 1 to 20 carbon atoms having perfluoroalkyl or perfluoropolyether group, A is a monovalent linkage, B is a divalent linkage,
- C, D and E each are a linkage containing at least one group selected from the following formulae (1) to (13) and optionally another group, said other group, if present, is an alkyl and/or alkylene group, C and E are monovalent linkages and D is a divalent linkage, with the proviso that E is a monovalent linkage in which the total number of atoms other than hydrogen and halogen atoms is at least 8,
- x is 0 or a positive number,
- wherein R1 to R9 are each independently a monovalent group selected from the class consisting of hydrogen, halogen, hydroxyl, unsubstituted monovalent hydrocarbon or alkoxy groups of 1 to 20 carbon atoms, and monovalent organic groups of 1 to 20 carbon atoms having perfluoroalkyl or perfluoropolyether group,
- X is a divalent group represented by the formula:
- wherein R10 to R11 are each independently selected from the class consisting of hydrogen, halogen, unsubstituted monovalent hydrocarbon groups of 1 to 20 carbon atoms, and monovalent organic groups of 1 to 20 carbon atoms having perfluoroalkyl or perfluoropolyether group, or R10 to R11, taken together, may form a carbocyclic or heterocyclic ring, and “n” is an integer of at least 2.
11 more elements
Dependencies are inferred from the claim text.