Reforming Catalyst with Chelated Promoter
AssigneeUop LLC
InventorsLeonid Galperin, Frank Modica, Thomas McBride
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Abstract
A process for preparing a naphtha reforming catalyst has been developed. The process involves the use of a chelating ligand such as ethylenediaminetetraacetic acid (EDTA). The aqueous solution of the chelating ligand and a tin compound is used to impregnate a support, e.g., alumina extrudates. A platinum-group metal is also an essential component of the catalyst. Rhenium may also be a component. A reforming process using the catalyst has enhanced yield, activity, and stability for conversion of naphtha into valuable gasoline and aromatic products.
Claims10
A process for preparing a catalyst suitable for naphtha reforming comprising a stannous tin component, a platinum-group metal component, and a rhenium component, having the stannous tin component uniformly distributed throughout a solid refractory oxide support, the process comprising:
- a) preparing a chelate-tin aqueous solution containing a chelating agent and a stannous tin compound;
- b) heating said chelate-tin solution for a time of about 5 minutes to about 5 hours at a temperature of about 40° to about 100° C.;
- c) preparing an acidic aqueous solution containing a platinum-group compound and a rhenium compound;
- d) impregnating a solid refractory oxide support with said acidic solution to give a first impregnated solid support;
- e) impregnating said first impregnated solid support with said chelate-tin solution to give a second impregnated solid support;
- f) calcining the second impregnated solid support at a temperature of about 300° to about 850° C. for a time of about 10 minutes to about 18 hours to give a calcined catalyst;
- and
- g) reducing the calcined catalyst at a temperature of about 300° to about 850° C. for a time of about 30 minutes to about 18 hours, under a reducing atmosphere, thereby providing said catalyst suitable for naphtha reforming.
Dependencies are inferred from the claim text.