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US 2007/0190344 A1Published application
Verification of translation
AssigneesChisso Petrochemical Corporation, Chisso Corporation
InventorsJyun-ichi Inagaki, Yasuyuki Sasada, Takashi Kato
Life of this patent
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Abstract
A compound represented by Formula (1) and a polymer obtained using the compound: wherein R1 is phenyl which may have substituents, Q1 is hydrogen, halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms, Q2 is a group represented by Formula (2): wherein the code < represents a bonding point with silicon, l, m, n and p are independently 0, 1, 2 or 3, and A1 to A4, Z0 to Z4 and Y1 are defined in the specification.
Claims40
A compound represented by Formula (1):
- wherein R1 is phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms;
- in the alkyl having 1 to 5 carbon atoms, optional —CH2— which, is not adjacent to each other may be replaced by —O—, and optional hydrogen may be replaced by halogen;
- Q1 is hydrogen, halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms;
- in the alkyl having 1 to 10 carbon atoms and the alkyl having 1 to 5 carbon atoms which may be a substituent of phenyl, optional —CH2— which is not adjacent to each other may be replaced by —O—, —CH═CH— or —C≡C—, and optional hydrogen may be replaced by halogen;
- and Q2 is a group represented by Formula (2):
- wherein the code < represents a bonding point with silicon;
- l, m, n and p are independently 0, 1, 2 or 3;
- A1, A2, A3 and A4 are independently a single bond, 1,4-cyclohexylene, 1,4-cyclohexenylene, a condensed ring group having 6 to 10 carbon atoms which is a divalent group, or 1,4-phenylene;
- in these rings, optional —CH2— which is not adjacent to each other may be replaced by —O—, and optional —CH═ may be replaced by —N═;
- optional hydrogen in all rings may be replaced by halogen, —CN, —NO2 or alkyl having 1 to 5 carbon atoms;
- in the alkyl having 1 to 5 carbon atoms, optional —CH2— which is not adjacent to each other may be replaced by —O—, —CH═CH— or —C≡C—, and optional hydrogen may be replaced by halogen;
- Z0, Z1, Z2 and Z3 are independently a single bond, —CH═CH—, —C≡C—, —COO—, —OCO—, or alkylene in which the number of carbon atoms is 1 to 20, and optional —CH2— may be replaced by —O—, —S—, —NH—, —SiR22—, —SiR22O—, —OSiR22—, —OSiR22O—, —SiR22OSiR22—, —COO—, —OCO—, —CH═CH— or —C≡C—;
- R2 is halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl, or phenyl in which optional hydrogen may be replaced by halogen, or alkyl having 1 to 5 carbon atoms;
- in the alkyl having 1 to 10 carbon atoms and the alkyl having 1 to 5 carbon atoms which may be a substituent of phenyl, optional —CH2— which is not adjacent to each other may be replaced by —O—, —CH═CH— or —C≡C—, and optional hydrogen may be replaced by halogen;
- Z4 is a single bond, —CH═CH—, —C≡C—, —COO—, —OCO—, or alkylene in which the number of carbon atoms is 1 to 20 and optional —CH2— which is not adjacent to each other may be replaced by —O—, —COO—, —OCO—, —CH═CH— or —C≡C—;
- and Y1 is halogen, —OM1-, —SM1-, —CHO, —COOR3—, —CSOR3—, —CSSR3—, —NHR4—, —COX1—, —CSX1—, —OCOX1—, —OCOOR3—, —N═C═O, —CN, —C≡CH, —CR5═CH2, —CR5═CR6COOR3, —CH═CR5CR6═CH2, —SO2X1, —SiR22X1, —SiR22OR3, —SiR22OCOR7, —SiR22OC(CH3)═CH2, —SiR22ON═CR7R8, —SiR22NR7R8, or any one of groups shown below:
- in these groups related to Y1, M1 is hydrogen or alkaline metal;
- R3 is hydrogen, alkaline metal, or alkyl in which the number of carbon atoms is 1 to 10, optional —CH2— which is not adjacent to each other may be replaced by —O—, and optional hydrogen may be replaced by halogen;
- R4 is hydrogen, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl, alkyl in which the number of carbon atoms is 1 to 10, optional —CH2— which is not adjacent to each other may be replaced by —O— and optional hydrogen may be replaced by halogen, or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms;
- in the alkyl having 1 to 5 carbon atoms which may be a substituent of phenyl, optional —CH2— which is not adjacent to each other may be replaced by —O—, —CH═CH— or —C≡C—, and optional hydrogen may be replaced by halogen;
- X1 is halogen;
- R5, R6 and X2 are independently hydrogen, halogen, —CN, or alkyl in which the number of carbon atoms is 1 to 10 optional —CH2— which is not adjacent to each other may be replaced by —O—, and optional hydrogen may be replaced by halogen;
- R7 and R8 are independently alkyl having 1 to 10 carbon atoms;
- G1 is a trivalent organic group;
- R9 is hydrogen or alkyl having 1 to 5 carbon atoms;
- q is 1 or 0;
- r is an integer of 0 to 5;
- and t is an integer of 1 to 5.
25 more elements
A polymer having a structural unit represented by Formula (3):
- wherein R1 is phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms;
- in the alkyl having 1 to 5 carbon atoms, optional —CH2—, which is not adjacent to each other, may be replaced by —O—, and optional hydrogen may be replaced by halogen;
- Q1 is hydrogen, halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl, or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms;
- in the alkyl having 1 to 10 carbon atoms and alkyl having 1 to 5 carbon atoms which is a substituent of phenyl, optional —CH2—, which is not adjacent to each other, may be replaced by —O—, —CH═CH— or —C≡C—, and optional hydrogen may be replaced by halogen;
- and Q3 is a group represented by Formula (4):
- wherein a code < represents a bonding point with silicon;
- l, m, n and p are independently 0, 1, 2 or 3;
- A1, A2, A3 and A4 are independently a single bond, 1,4-cyclohexylene, 1,4-cyclohexenylene, a condensed ring group having 6 to 10 carbon atoms which is a divalent group, or 1,4-phenylene;
- in these rings, optional —CH2—, which is not adjacent to each other, may be replaced by —O—, and optional —CH═ may be replaced by —N═;
- optional hydrogen in all rings may be replaced by halogen, —CN, —NO2 or alkyl having 1 to 5 carbon atoms;
- in the alkyl having 1 to 5 carbon atoms, optional —CH2—, which is not adjacent to each other, may be replaced by —O—, —CH═CH— or —C≡C—, and optional hydrogen may be replaced by halogen;
- Z0, Z1, Z2 and Z3 are independently a single bond, —CH═CH—, —C≡C—, —COO—, —OCO— or alkylene in which the number of carbon atoms is 1 to 20 and optional —CH2— may be replaced by —O—, —S—, —NH—, —SiR22—, —SiR22O—, —OSiR22—, —OSiR22O—, —SiR22OSiR22—, —COO—, —OCO—, —CH═CH— or —C≡C—;
- R2 is halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl, or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms;
- in the alkyl having 1 to 10 carbon atoms and alkyl having 1 to 5 carbon atoms which is a substituent of phenyl, optional —CH2—, which is not adjacent to each other, may be replaced by —O—, —CH═CH— or —C≡C—, and optional hydrogen may be replaced by halogen;
- Z5 is a single bond, —CH═CH—, —C≡C—, —COO—, —OCO— or a group represented by —W1-T1-;
- W1 is a single bond or alkylene in which the number of carbon atoms is 1 to 20 and optional —CH2—, which is not adjacent to each other, may be replaced by —O—, —COO—, —OCO—, —CH═CH— or —C≡C—;
- and T1 is —O—, —S—, —SiR22—, —SiR22O—, —OSiR22—, —OSiR22O—, —SiR22OSiR22—, —CO—, —COO—, —OCO—, —CSO—, —OCS—, —CONR0—, —NR10CO—, —CONR10O—, —ONR10CO—, —OCONR10—, —NR10CONR10—, —NR10COO—, —OCOO—, —CH(OH)CH2—, —CH2CH(OH)—, —CH═CH—, —CH2CR5═CR6CH2—, —C≡C—, —SO2—, —SO2O—, —OSO2—, —SO2S—, —SSO2—, —SO2NR7—, —NR10SO2—, or any one of groups shown below:
- in the groups related to T1, R2 is the same as described above;
- R10 is hydrogen, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl, alkyl in which the number of carbon atoms is 1 to 10, and optional hydrogen may be replaced by halogen, or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms;
- in the alkyl having 1 to 5 carbon atoms which is a substituent of phenyl, optional —CH2—, which is not adjacent to each other, may be replaced by —O—, —CH═CH— or —C≡C—, and optional hydrogen may be replaced by halogen;
- R5, R6 and X2 are independently hydrogen, halogen, —CN or alkyl in which the number of carbon atoms is 1 to 10, optional —CH2—, which is not adjacent to each other, may be replaced by —O—, and optional hydrogen may be replaced by halogen;
- G1 is a trivalent organic group;
- G2 is a part of tricarboxylic acid—derivative's residue or a part of tetracarboxylic acid—derivative's residue;
- R9 is hydrogen or alkyl having 1 to 5 carbon atoms;
- q is 1 or 0;
- r is an integer of 0 to 5;
- and t is an integer of 1 to 5.
24 more elements
Dependencies are inferred from the claim text.