Fluorosulphonated elastomers with low glass transition based of vinylidene fluoride
AssigneeHydro-Quebec
InventorsBruno AMEDURI, Michel Armand, Mario Boucher, Abdellatif Manseri
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Abstract
The present invention describes the synthesis of new sulforated fluorinated elastomers having very low glass transition temperatures (Tg), a good resistance to bases, oils and fuels and good properties of workability. These elastomers contain, by way of example, from 80 to 60 mole % of vinylidene fluoride (VDF) and 20 to 40 mole % of perfluoro(4-methyl-3,6-dioxaoct-7-ene)sulfonyl fluoride (PFSO2F). In this case, they are prepared by radical copolymerisation of VDF and PFSO2F in the presence of different organic initiators, for example, peroxides, peresters or diazo compounds.
Claims18
1-32. (canceled)
Sulfonated fluorinated elastomer having a glass transition temperature (Tg) of between −32 and −36° C. and containing a copolymer of vinylidene fluoride (VDF) and at least one monomer selected from the group consisting of perfluorosulfonyl fluoride ethoxy propyl vinyl ether (PSEPVE) and perfluoro(4-methyl-3,6-dioxaoct-7-ene)sulfonyl fluoride (PFSO2F),
- wherein the sulfonated fluorinated elastomer does not comprise tetrafluoroethylene, hexafluoropropene and a monomer having a siloxane group.
Dependencies are inferred from the claim text.