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US 2007/0184603 A1Published application
Method of fabricating semiconductor integrated circuit device
AssigneeRenesas Technology Corp.
InventorsShinji Nishihara, Shuji Ikeda, Naotaka Hashimoto, Hiroshi Momiji, Hiromi Abe, Shinichi Fukada, Masayuki Suzuki
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Abstract
A Co silicide layer having a low resistance and a small junction leakage current is formed on the surface of the gate electrode, source and drain of MOSFETS by silicidizing a Co film deposited on a main plane of a wafer by sputtering using a high purity Co target having a Co purity of at least 99.99% and Fe and Ni contents of not greater than 10 ppm, preferably having a Co purity of 99.999%.
Claims10
A method of fabricating a semiconductor integrated circuit device, comprising the steps of:
- (a) forming an isolation groove in a silicon surface of a first major surface of a wafer, so as to divide the silicon surface into two regions which are to be first and second regions;
- (b) after step (a), forming a first insulating film of silicon oxide by chemical vapor deposition in such manner that the first insulating film covers the silicon surface;
- (c) after step (b), polishing the first insulating film so as to planarize the first major surface of the wafer;
- (d) after step (c), forming two gate electrodes having a gate length less than 250 nm, to be N- and P-type gate electrodes, respectively over the first and second regions, each of said two gate electrodes having a silicon film to be a silicon conductive film;
- (e) forming N-type source and drain regions in the first region, said N-type source and drain regions to constitute a first insulated gate field effect transistor together with the N-type gate electrode and a pair of first insulating side walls;
- (f) forming P-type source and drain regions in the second region, said P-type source and drain regions to constitute a second insulated gate field effect transistor together with the P-type gate electrode and a pair of second insulating side walls;
- (g) after the steps (d), (e), and (f), exposing surface portions of the silicon surface over said N-type and P-type source regions and drain regions;
- (h) after the step (g), depositing a cobalt film covering at least the exposed surface portions, by sputtering, from a cobalt sputtering target which, apart from carbon and oxygen impurities, is at least 99.99 wt. % pure, wherein a sum of Fe and Ni in the cobalt film sputtering target is not greater than 50 ppm by weight, and wherein the sputtering is performed in such a manner that the composition of the deposited cobalt film is substantially the same as that of the cobalt sputtering target;
- (i) after the step (h), performing first rapid thermal annealing at a first temperature to the first major surface formed with the cobalt film so as to form cobalt monosilicide films over the surface portions, leaving a remaining cobalt film not formed into cobalt monosilicide, wherein the first temperature is a temperature that creep-up across the first and second insulating side walls substantially does not take place;
- (j) after the step (i), removing the remaining cobalt film by wet etching;
- (k) after the step (j), performing second rapid thermal annealing at a second temperature higher than the first temperature to the first major surface so as to form cobalt disilicide films over the surface portions;
- (l) after the step (k), forming a second insulating film over the silicon surface;
- (m) after the step (l), forming a third insulating film over the second insulating film such that the third insulating film has a thickness greater than a thickness of the second insulating film;
- and
- (n) after the step (l), performing a thermal annealing to the wafer.
12 more elements
Dependencies are inferred from the claim text.