Recovery of steel from contaminated scrap
OwnerNoel Warnerinventor
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OwnerNoel Warnerinventor
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This invention provides a method for overcoming the adverse effects of disintegration of molten steel streams due to sub-surface growth of carbon monoxide bubbles when exposed to reduced pressures and thus permits refining of liquid scrap much the same way as if it were a quiescent liquid melt. Steel scrap contaminated with copper, tin, zinc and organics, such as PVC coating, is preheated and melted continuously using melt circulation and then continuously refined in-line to yield high quality liquid steel and separate non-ferrous metal byproducts by straightforward physical desorption under reduced pressure using an inert strip gas within a desorber and then subsequent iron vapour condensation by direct contacting with liquid steel followed by selective condensation of copper initially and then recovery of tin. Formation of dioxins from scrap containing chlorine is precluded by inline scrubbing of pyrolysis gas formed during scrap preheating. The initial melting of preheated scrap employs melt circulation and gas combustion rather than fossil fuel generated electricity and is thus inherently energy efficient.
A method for recovering high quality steel and non-ferrous metals from contaminated steel scrap by in-line continuous processing of liquid scrap without the disruptive influence of sub-surface nucleation and growth of carbon monoxide bubbles, a characteristic of steel melts containing dissolved oxygen and carbon, which also avoids high vacuum evaporative distillation but rather employs straightforward physical desorption into an inert strip gas at reduced pressure by ensuring that the carbon/oxygen reaction is under control or its effects unable to disrupt the functionality of barometric legs for continuously transporting molten steel product from reduced pressure vessels or desorbers back to around atmospheric pressure into low level back-mixed liquid sumps by recirculating melt between the basal region of such vessels and these sumps using an adaptation of established RH vacuum degassing practice employing an upleg and a downleg for melt circulation at a rate many times that of the steel product rate and at least in the region of 20 tonnes per minute in conjunction with product metal removal from the liquid sumps, which for 500,000 tonnes per annum of steel production equates to about 0.95 tonnes per minute and thereby ensuring operability of the desorber, continuity of flow of liquid metal as the dispersed phase and the availability of the full diffusional driving forces characteristic of non back-mixed gas/liquid contacting.
Dependencies are inferred from the claim text.