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US 2007/0179059 A1Published application
2-(Poly-substituted aryl)-6-amino-5-halo-4-pyrimidinecarboxylic acids and their use as herbicides
AssigneeDow AgroSciences LLC
InventorsJeffrey Epp, James Ruiz, Paul Schmitzer, Terry Balko, Thomas Siddall, Carla Yerkes
Life of this patent
Estimating the term…
Abstract
6-Amino-5-halo-4-pyrimidinecarboxylic acids having poly-substituted aryl substituents in the 2-position, and their amine and acid derivatives, are potent herbicides demonstrating a broad spectrum of weed control.
Claims14
A compound of the formula I
- wherein
- Q represents a halogen;
- R1 and R2 independently represent H, C1-C6 alkyl, C3-C6 alkenyl, C3-C6 alkynyl, hydroxy, C1-C6 alkoxy, amino, C1-C6 acyl, C1-C6 carboalkoxy, C1-C6 alkylcarbamyl, C1-C6 alkylsulfonyl, C1-C6 trialkylsilyl or C1-C6 dialkyl phosphonyl or R1 and R2 taken together with N represent a 5- or 6-membered saturated ring;
- and
- Ar represents a polysubstituted aryl group selected from the group consisting of
- a)
- wherein
- W1 represents F or Cl;
- X1 represents C1-C4 alkyl, C1-C4 alkoxy, C1-C4 alkylthio, C1-C4 haloalkyl, C1-C4 haloalkoxy, C1-C4 haloalkylthio or —NR3R4;
- Y1 represents halogen or C1-C4 haloalkyl or, when X1 and Y1 are taken together, represents —O(CH2)nO— wherein n=1 or 2;
- and
- R3 and R4 independently represent H or C1-C4 alkyl;
- b)
- wherein
- W2 represents F or Cl;
- X2 represents C1-C4 alkyl, C1-C4 alkoxy, C1-C4 alkylthio, C1-C4 haloalkyl, C1-C4 haloalkoxy, C1-C4 haloalkylthio or —NRO3R4;
- Y2 represents halogen or C1-C4 haloalkyl or, when X2 and Y2 are taken together, represents —O(CH2)nO— wherein n=1 or 2;
- and
- R3 and R4 independently represent H or C1-C4 alkyl;
- and
- c)
- wherein
- Y3 represents halogen or C1-C4 haloalkyl or, when Y3 and Z3 are taken together, represents —O(CH2)nO— wherein n=1 or 2;
- Z3 represents C1-C4 alkyl, C1-C4 alkoxy, C1-C4 alkylthio, C1-C4 haloalkyl, C1-C4 haloalkoxy, C1-C4 haloalkylthio or —NR3R4;
- and
- R3 and R4 independently represent H or C1-C4 alkyl;
- and agriculturally acceptable derivatives of the carboxylic acid group.
24 more elements
Dependencies are inferred from the claim text.