Fuel cell components having porous electrodes
AssigneeSaint-Gobain Ceramics & Plastics, Inc.
InventorsF. Mahoney, John Pietras
Life of this patent
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Abstract
An SOFC component includes a first electrode, an electrolyte overlying the first electrode, and a second electrode overlying the electrolyte. The second electrode includes a bulk layer portion and a functional layer portion, the functional layer portion being an interfacial layer extending between the electrolyte and the bulk layer portion of the second electrode, wherein the bulk layer portion has a bimodal pore size distribution.
Claims68
An SOFC component, comprising:
- a first electrode;
- an electrolyte overlying the first electrode;
- and
- a second electrode overlying the electrolyte, the second electrode comprising a bulk layer portion and a functional layer portion, the functional layer portion being an interfacial layer extending between the electrolyte and the bulk layer portion of the second electrode, wherein the bulk layer portion has a bimodal pore size distribution.
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An SOFC component, comprising:
- a first electrode layer;
- an electrolyte layer overlying the first electrode layer;
- and
- a second electrode layer overlying the electrolyte layer, the second electrode layer having a bimodal grain size distribution such that the second electrode layer comprises fine grains having an average grain size Gf and coarse grains having an average grain size Gc, wherein Gc/Gf is not less than about 1.5.
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A method of forming a SOFC component, comprising:
- forming a first electrode;
- forming an electrolyte overlying the first electrode;
- and
- forming a second electrode overlying the electrolyte, the second electrode comprising powder, the powder comprising agglomerates formed of grains;
- heat treating the first electrode, the electrolyte and the second electrode to form the SOFC component
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A method of forming a SOFC component, comprising:
- forming a green first electrode layer;
- forming a green electrolyte layer overlying the first electrode layer;
- and
- forming a green second electrode layer overlying the green electrolyte layer the second electrode layer having a relative green density ρg;
- sintering the first electrode layer, the electrolyte layer and the second electrode layer to densify the layers, the green second electrode layer forming a densified second electrode layer, the densified second electrode layer having a relative sintered density ρs and having porosity, the porosity of the densified second electrode layer being achieved without fugitive pore formers.
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Dependencies are inferred from the claim text.