2,7-Carbazolenevinylene derivatives as novel materials in producing organic based electronic devices
AssigneeNational Research Council of Canada
InventorsNicolas Drolet, Jean-Francois Morin, Ye Tao, Mario Leclerc, Kathleen Sirois
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Abstract
Organic Field Effect Transistor (OFET), an Organic Light Emitting Diode (OLED), an and an Organic Photovoltaic Cell (OPC) including as active material a congugated oligomeric or polymeric 2,7-carbazolenevinylene derivative described by the formula (I) or (II): Such OFETs, OLEDs and OPCs have improved devices properties and efficiencies.
Claims21
An organic based electronic device having as an active material a conjugated oligomeric or polymeric 2,7-carbazolenevinylene derivative described by the formula (I):
- wherein n is an integer ≧3, R represents a substituant that is a hydrogen, or linear or branched alkyl group containing 1 to 20 carbon atoms, linear or branched alkoxy group containing 1 to 20 carbon atoms, poly(ethyleneoxy), cyano, aryl group, amide group or benzoyl group, and A, B are any type of end-cap groups selected from the group consisting of hydrogen, linear or branched alkyl group containing 1 to 20 carbon atoms, linear or branched alkoxy group containing 1 to 20 carbon atoms, cyano group, halogen group, monovalent aromatic group, and monovalent aromatic complex ring group having one nitrogen atom as a hetero-atom.
An organic based device from the group;
- an Organic Field Effect Transistor (OFET), an Organic Light Emitting Diode (OLED), and an Organic Photovoltaic Cell (OPC), the device comprising active material including a conjugated 2,7-carbazolenevinylene derivative where 2,7-carbazolenevinylene monomers can also be alternated with other monomers to form oligomeric or polymeric materials according to the general formula (II):
- wherein n is an integer ≧3, R represents a substituant that is a hydrogen, or linear or branched alkyl group containing 1 to 20 carbon atoms, linear or branched alkoxy group containing 1 to 20 carbon atoms, poly(ethyleneoxy), cyano, aryl, amide or benzoyl, x is an integer between 1 to 1000, y is an integer between 0 to 1000, Z is any type of comonomer selected from the group consisting of ethylene, acethylene, C6-C22 mononuclear/polynuclear aromatic, C2-C10 mononuclear/polynuclear heterocyclic groups and tertiary arylamines, and A, B are any type of end-cap groups selected from the group consisting of hydrogen, linear or branched alkyl group containing 1 to 20 carbon atoms, linear or branched alkoxy group containing 1 to 20 carbon atoms, cyano group, halogen group, monovalent aromatic group, and monovalent aromatic complex ring group having one nitrogen atom as a hetero-atom.
Dependencies are inferred from the claim text.