Method for the direct conversion of a charge containing olefins comprising a minimum of four or five carbon atoms, for producing propylene
AssigneeInstitut Francais du Petrole
InventorsJean Duplan, Sylvie Lacombe
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Abstract
The invention concerns a process for producing propylene, especially from a light steam cracking and/or catalytic cracking cut, preferably comprising both butenes and pentenes, said process comprising a step for moving bed catalytic cracking with a catalyst regeneration loop. The catalyst comprises at least one zeolite with a zeolitic composition with a Si/Al ratio which is preferably less than 130. The invention can produce a high conversion with a good yield of propylene at a high space velocity, meaning that the volume of catalyst can be reduced.
Claims10
A process for direct conversion, by catalytic cracking, of a light olefinic hydrocarbon feed comprising at least 80% by weight of hydrocarbons containing at most 12 carbon atoms for the production of propylene, said process comprising direct cracking of the feed on a supported catalyst comprising at least one zeolite comprising silicon and aluminum and having form selectivity, from the group constituted by zeolites with one of the following structure types:
- MEL, MFI;
- NES, EUO, FER, CHA, MFS, MWW, and from the following zeolites:
- NU-85, NU-86, NU-88 and IM-5, comprising circulating the feed at a temperature in the range about 480° C. to 620° C. in at least one reactor on a granular moving bed of said catalyst, extracting from the lower portion of the reactor, continuously or discontinuously, a flow of catalyst comprising a carbonaceous deposit, transferring said catalyst to a regeneration zone where it undergoes at least one controlled oxidation step, then downstream of the regeneration zone, re-introducing the catalyst comprising a reduced amount of carbonaceous deposit directly or indirectly into the upper portion of said reactor, the catalyst used being such that the zeolites from said group have a Si/Al ratio in the range 40 to 130.
Dependencies are inferred from the claim text.