Rare earth complex excellent in thermal resistance
OwnerKazuhiro Manseki, Yasuchika Hasegawa +1inventors
InventorsKazuhiro Manseki, Yasuchika Hasegawa, Shozo Yanagida
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Abstract
The present invention provides a fluorescent substance excellent in thermal resistance, which can be uniformly dispersed into plastic materials, and has a high fluorescence intensity even after experienced heat history in plastic forming processes. More specifically, the present invention provides a fluorescent substance containing a rare earth complex having benzophenone or benzoyl substituted with an alkyl group, a cycloalkyl group, an acyl group or an alkoxy group having a carbon number of 1 to 20 as a skeletal structure, in which a plurality of rare earth ions are coordinated with one or more types of molecules having a photosensitizing function.
Claims14
A multinuclear rare earth complex formed by coordinating one or more types of molecules having a photosensitizing function and a vibrational energy quenching-suppressing function to a plurality of rare earth ions, which is represented by the general formula:
- LpL′q(Ln)rXs,
- wherein
- L is a ligand having a photosensitizing function represented by the general formula:
- wherein R1, R2, R3, R4 and R5 are independently hydrogen, a hydroxide group, a substituted or unsubstituted amino group, a substituted or unsubstituted aryl group, a nitro group, a cyano group, an alkyl group or a cycloalkyl group represented by —R, an alkoxy group represented by —OR, or an acyl group represented by —C(C═O)R, where R is a substituted or unsubstituted alkyl group or cycloalkyl group having a carbon number of 1 to 20;
- Y1 is —OH;
- and
- Y2 is ═O;
- is an integer of 1 to 40;
- L′ is a ligand which is a hydroxide ion;
- q is an integer of 0 to 8;
- Ln is a rare earth ion;
- r is an integer of 2 to 20, where a plurality of Ln may be different from each other;
- X is O, —OH, S, —SH, Se or Te;
- s is an integer of 1 to 20, where a plurality of X may be different from each other when s is an integer of 2 to 20;
- and further, the integers p, r and s have a relationship indicated by the expression:
- 1≦p/r≦4, 1≦r/s≦4 [expression 1]
- wherein a coordination manner of L to Ln is:
- Coordination Manner (A) where both Y1 and Y2 bind to the identical Ln;
- Coordination Manner (B) where Y1 and Y2 bind to different Ln each other;
- and a combination thereof, wherein when Y1 coordinates to Ln, a proton leaves from —OH represented by Y1 to form —O—, thereby L coordinates to Ln via —O—.
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Dependencies are inferred from the claim text.