Catalyst for oxidation or ammoxidation
AssigneeAsahi Kasei Chemicals Corporation
InventorsSatoru Komada, Sadao Shoji
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Abstract
Disclosed is a catalyst for use in catalytic oxidation or ammoxidation of propane or isobutane in the gaseous phase, which comprises an oxide containing, in specific atomic ratios, molybdenum (Mo), vanadium (V), niobium (Nb) and antimony (Sb), wherein the oxide catalyst has a reduction ratio of from 8 to 12% and a specific surface area of from 5 to 30 m2/g. Also disclosed is a process for efficiently producing this catalyst.
Claims21
A catalyst for use in catalytic oxidation or ammoxidation of propane or isobutane in the gaseous phase, which comprises an oxide represented by the following formula (1):
- Mo1VaNbbSbcOn (1)
- wherein:
- a, b, c and n are, respectively, the atomic ratios of vanadium (V), niobium (Nb), antimony (Sb) and oxygen (O), relative to molybdenum (Mo),
- wherein:
- 0.1≦a≦1,
- 0.01≦b≦1,
- 0.01≦c≦1, and
- n is the number of oxygen atoms required to satisfy the valence requirements of the other component elements present,
- said catalyst having a reduction ratio of from 8 to 12% and a specific surface area of from 5 to 30 m2/g,
- said reduction ratio being represented by the following formula (2):
- reduction ratio (%)=((n0−n)/n0)×100 (2)
- wherein:
- n is as defined for formula (1), and
- n0 is the number of oxygen atoms required when the other component elements in said oxide of formula (1) respectively exhibit the maximum oxidation numbers of the other component elements.
Dependencies are inferred from the claim text.