Low color polyisobutylene succinic anhydride-derived emulsifiers
OwnerClaire Hollingshurst, David Price +3inventors
InventorsClaire Hollingshurst, David Price, Thomas Steckel, Brian Filippini, Nai Huang
Life of this patent
Estimating the term…
Abstract
The invention relates to new synthesis techniques to form emulsifiers of low color from maleic anhydride and polymers of isobutylene. These emulsifiers satisfy a need for a low color component with a long oil compatible hydrophobic tail and a short hydrophilic moiety.
Claims11
A composition comprising;
- a) a reaction product from the reaction of a polyolefin polymer having at least 20 carbon atoms with maleic anhydride, maleic acid, fumaric acid, or their esters or combinations thereof having a color on the Gardner Color scale of equal to 2 or less than 3,
- b) optionally further reacted with a polyol, alkanolamine, amine, or ammonia or another base, or combinations thereof and optionally, including a diluent oil.
A composition comprising:
- a) a reaction product from the reaction of a polyolefin polymer having at least 20 carbon atoms with maleic anhydride and/or maleic acid forming a succinic anhydride functionalized polyolefin,
- b) further reacting said functionalized polyolefin with a polyol, alkanolamine, amine, or ammonia or another base, or combinations thereof, and
- c) optionally diluting with a diluent oil,
- wherein said reaction product of steps “a” and “b” has a color on the Garner Color scale of equal to or less than 2.
A process for making a low color polyisobutylene succinic anhydride or surfactant therefrom from reacting a polyolefin with maleic anhydride, maleic acid, fumaric acid, or their esters comprising:
- reacting a polyolefin having at least 20 carbon atoms and at least one carbon-to-carbon double bond with maleic anhydride in its anhydride or acid form or fumaric acid or the esters of maleic or fumaric acid in a molar ratio of total maleic anhydride, maleic acid, fumaric acid and their esters to polyolefin of less than 1.3 to 1;
- optionally further reacted with a polyol, alkanolamine, amine, or ammonia or another base, or combinations thereof;
- and
- optionally diluted with a diluent oil;
- and wherein the color of the resulting reaction product is equal to or less than 2 on the Gardner Color scale.
A process according to claim, wherein said reaction product is substantially the product of a thermal reaction between a polyolefin and maleic anhydride.
11-24. (canceled)
Dependencies are inferred from the claim text.